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Synthesis of benzo[d]imidazo[2,1-b]benzoselenoazoles: Cs(2)CO(3)-mediated cyclization of 1-(2-bromoaryl)benzimidazoles with selenium
The synthesis of benzimidazo[2,1-b]benzoselenoazoles is described. The novel ring-closure reaction of 1-(2-bromoaryl)benzimidazoles with Se powder is promoted by Cs(2)CO(3) (2 equiv) in DMF at 150 °C. Moreover, the obtained tetracyclic heterocycles are all novel compounds. Single-crystal X-ray analy...
Autores principales: | Matsumura, Mio, Kitamura, Yuki, Yamauchi, Arisa, Kanazawa, Yoshitaka, Murata, Yuki, Hyodo, Tadashi, Yamaguchi, Kentaro, Yasuike, Shuji |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6720659/ https://www.ncbi.nlm.nih.gov/pubmed/31501670 http://dx.doi.org/10.3762/bjoc.15.199 |
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