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Computational Mechanistic Insights on the NO Oxidation Reaction Catalyzed by Non-Heme Biomimetic Cr-N-Tetramethylated Cyclam Complexes
The conversion reaction of NO to NO(3)(−) ion catalyzed by the end-on [Cr(III)(n-TMC)(O(2))(Cl)](+) superoxo and side-on [Cr(IV)(n-TMC)(O(2))(Cl)](+) peroxo non-heme complexes (n = 12, 13, 14 and 15), which are biomimetic systems of nitric oxide dioxygenases (NODs), has been explored using a computa...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6721035/ https://www.ncbi.nlm.nih.gov/pubmed/31416223 http://dx.doi.org/10.3390/ijms20163955 |