Surface Engineering of Fluoropolymer Films via the Attachment of Crown Ether Derivatives Based on the Combination of Radiation-Induced Graft Polymerization and the Kabachnik–Fields Reaction

In this manuscript, we present the successful attachment of crown ether moieties onto fluoropolymer surfaces, via the combination of radiation-induced graft polymerization and a subsequent surface Kabachnik–Fields three-component reaction. The obtained crown ether-tethered fluoropolymer films exhibi...

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Autores principales: Omichi, Masaaki, Yamashita, Shuhei, Okura, Yamato, Ikutomo, Ryuta, Ueki, Yuji, Seko, Noriaki, Kakuchi, Ryohei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6723282/
https://www.ncbi.nlm.nih.gov/pubmed/31409049
http://dx.doi.org/10.3390/polym11081337
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author Omichi, Masaaki
Yamashita, Shuhei
Okura, Yamato
Ikutomo, Ryuta
Ueki, Yuji
Seko, Noriaki
Kakuchi, Ryohei
author_facet Omichi, Masaaki
Yamashita, Shuhei
Okura, Yamato
Ikutomo, Ryuta
Ueki, Yuji
Seko, Noriaki
Kakuchi, Ryohei
author_sort Omichi, Masaaki
collection PubMed
description In this manuscript, we present the successful attachment of crown ether moieties onto fluoropolymer surfaces, via the combination of radiation-induced graft polymerization and a subsequent surface Kabachnik–Fields three-component reaction. The obtained crown ether-tethered fluoropolymer films exhibited an ammonium cation capturing ability, owing to the host–guest interactions (i.e., hydrogen bonding) between the surface-anchored crown ethers and the guest ammonium cations.
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spelling pubmed-67232822019-09-10 Surface Engineering of Fluoropolymer Films via the Attachment of Crown Ether Derivatives Based on the Combination of Radiation-Induced Graft Polymerization and the Kabachnik–Fields Reaction Omichi, Masaaki Yamashita, Shuhei Okura, Yamato Ikutomo, Ryuta Ueki, Yuji Seko, Noriaki Kakuchi, Ryohei Polymers (Basel) Article In this manuscript, we present the successful attachment of crown ether moieties onto fluoropolymer surfaces, via the combination of radiation-induced graft polymerization and a subsequent surface Kabachnik–Fields three-component reaction. The obtained crown ether-tethered fluoropolymer films exhibited an ammonium cation capturing ability, owing to the host–guest interactions (i.e., hydrogen bonding) between the surface-anchored crown ethers and the guest ammonium cations. MDPI 2019-08-12 /pmc/articles/PMC6723282/ /pubmed/31409049 http://dx.doi.org/10.3390/polym11081337 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Omichi, Masaaki
Yamashita, Shuhei
Okura, Yamato
Ikutomo, Ryuta
Ueki, Yuji
Seko, Noriaki
Kakuchi, Ryohei
Surface Engineering of Fluoropolymer Films via the Attachment of Crown Ether Derivatives Based on the Combination of Radiation-Induced Graft Polymerization and the Kabachnik–Fields Reaction
title Surface Engineering of Fluoropolymer Films via the Attachment of Crown Ether Derivatives Based on the Combination of Radiation-Induced Graft Polymerization and the Kabachnik–Fields Reaction
title_full Surface Engineering of Fluoropolymer Films via the Attachment of Crown Ether Derivatives Based on the Combination of Radiation-Induced Graft Polymerization and the Kabachnik–Fields Reaction
title_fullStr Surface Engineering of Fluoropolymer Films via the Attachment of Crown Ether Derivatives Based on the Combination of Radiation-Induced Graft Polymerization and the Kabachnik–Fields Reaction
title_full_unstemmed Surface Engineering of Fluoropolymer Films via the Attachment of Crown Ether Derivatives Based on the Combination of Radiation-Induced Graft Polymerization and the Kabachnik–Fields Reaction
title_short Surface Engineering of Fluoropolymer Films via the Attachment of Crown Ether Derivatives Based on the Combination of Radiation-Induced Graft Polymerization and the Kabachnik–Fields Reaction
title_sort surface engineering of fluoropolymer films via the attachment of crown ether derivatives based on the combination of radiation-induced graft polymerization and the kabachnik–fields reaction
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6723282/
https://www.ncbi.nlm.nih.gov/pubmed/31409049
http://dx.doi.org/10.3390/polym11081337
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