Novel Ruthenium-Silver PTA-Based Polymers and Their Behavior in Water

New coordination polymers based on two metal-containing moieties Ru–Ag are synthesized: Na[RuCpX(PTA)-μ-(PTA)-1κP:2κ(2)N-AgX(2)](∞) (X = Cl (1), Br (2), I (3)). Characterization is performed by NMR, UV-visible and FT-IR spectroscopy, optical-electron microscopy, and elemental analyses (C, H, N, S)....

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Autores principales: Sierra-Martin, Benjamin, Serrano-Ruiz, Manuel, Scalambra, Franco, Fernandez-Barbero, Antonio, Romerosa, Antonio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6724013/
https://www.ncbi.nlm.nih.gov/pubmed/31357722
http://dx.doi.org/10.3390/polym11081249
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author Sierra-Martin, Benjamin
Serrano-Ruiz, Manuel
Scalambra, Franco
Fernandez-Barbero, Antonio
Romerosa, Antonio
author_facet Sierra-Martin, Benjamin
Serrano-Ruiz, Manuel
Scalambra, Franco
Fernandez-Barbero, Antonio
Romerosa, Antonio
author_sort Sierra-Martin, Benjamin
collection PubMed
description New coordination polymers based on two metal-containing moieties Ru–Ag are synthesized: Na[RuCpX(PTA)-μ-(PTA)-1κP:2κ(2)N-AgX(2)](∞) (X = Cl (1), Br (2), I (3)). Characterization is performed by NMR, UV-visible and FT-IR spectroscopy, optical-electron microscopy, and elemental analyses (C, H, N, S). Light scattering is employed to characterize the colloidal particles growth by polymer self-assembling. These structures are stable over a broad range of pH and exhibit thermally-driven swelling, thus resembling a typical thermosensitive hydrogel.
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spelling pubmed-67240132019-09-10 Novel Ruthenium-Silver PTA-Based Polymers and Their Behavior in Water Sierra-Martin, Benjamin Serrano-Ruiz, Manuel Scalambra, Franco Fernandez-Barbero, Antonio Romerosa, Antonio Polymers (Basel) Article New coordination polymers based on two metal-containing moieties Ru–Ag are synthesized: Na[RuCpX(PTA)-μ-(PTA)-1κP:2κ(2)N-AgX(2)](∞) (X = Cl (1), Br (2), I (3)). Characterization is performed by NMR, UV-visible and FT-IR spectroscopy, optical-electron microscopy, and elemental analyses (C, H, N, S). Light scattering is employed to characterize the colloidal particles growth by polymer self-assembling. These structures are stable over a broad range of pH and exhibit thermally-driven swelling, thus resembling a typical thermosensitive hydrogel. MDPI 2019-07-28 /pmc/articles/PMC6724013/ /pubmed/31357722 http://dx.doi.org/10.3390/polym11081249 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Sierra-Martin, Benjamin
Serrano-Ruiz, Manuel
Scalambra, Franco
Fernandez-Barbero, Antonio
Romerosa, Antonio
Novel Ruthenium-Silver PTA-Based Polymers and Their Behavior in Water
title Novel Ruthenium-Silver PTA-Based Polymers and Their Behavior in Water
title_full Novel Ruthenium-Silver PTA-Based Polymers and Their Behavior in Water
title_fullStr Novel Ruthenium-Silver PTA-Based Polymers and Their Behavior in Water
title_full_unstemmed Novel Ruthenium-Silver PTA-Based Polymers and Their Behavior in Water
title_short Novel Ruthenium-Silver PTA-Based Polymers and Their Behavior in Water
title_sort novel ruthenium-silver pta-based polymers and their behavior in water
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6724013/
https://www.ncbi.nlm.nih.gov/pubmed/31357722
http://dx.doi.org/10.3390/polym11081249
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