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Vinyl cyanide (CH(2)CHCN) in interstellar space: potential spectral lines for its detection

Vinyl cyanide is a molecule having planar geometry with electric dipole moment components, [Formula: see text] and [Formula: see text]. Thus, a-type transitions are very strong as compared to b-type transitions, and are considered in this investigation. The rotational levels for a-type transitions,...

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Autor principal: Sharma, Mohit K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6726722/
https://www.ncbi.nlm.nih.gov/pubmed/31508529
http://dx.doi.org/10.1016/j.heliyon.2019.e02384
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author Sharma, Mohit K.
author_facet Sharma, Mohit K.
author_sort Sharma, Mohit K.
collection PubMed
description Vinyl cyanide is a molecule having planar geometry with electric dipole moment components, [Formula: see text] and [Formula: see text]. Thus, a-type transitions are very strong as compared to b-type transitions, and are considered in this investigation. The rotational levels for a-type transitions, may be divided into two distinct groups: one group having odd values of [Formula: see text] and the other having even values of [Formula: see text]. Using the known values of rotational and centrifugal distortion constant along with the electric dipole moment [Formula: see text] , we have calculated energies of lower 120 rotational levels, having energy up to [Formula: see text] , for each group, and the probabilities for radiative transitions between the levels. These radiative transition probabilities in conjunction with the scaled values of collisional rate coefficients are used in the Sobolev Large Velocity Gradient analysis. Out of a large number of lines, we have selected the strongest ones. In the low lying levels, besides the 4 observed lines of CH(2)CHCN, we have discussed about 8 additional transitions, of which 2 showing the phenomenon of anomalous absorption and 6 showing emission feature are found. These lines may play important role for the search of vinyl cyanide in a cosmic object.
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spelling pubmed-67267222019-09-10 Vinyl cyanide (CH(2)CHCN) in interstellar space: potential spectral lines for its detection Sharma, Mohit K. Heliyon Article Vinyl cyanide is a molecule having planar geometry with electric dipole moment components, [Formula: see text] and [Formula: see text]. Thus, a-type transitions are very strong as compared to b-type transitions, and are considered in this investigation. The rotational levels for a-type transitions, may be divided into two distinct groups: one group having odd values of [Formula: see text] and the other having even values of [Formula: see text]. Using the known values of rotational and centrifugal distortion constant along with the electric dipole moment [Formula: see text] , we have calculated energies of lower 120 rotational levels, having energy up to [Formula: see text] , for each group, and the probabilities for radiative transitions between the levels. These radiative transition probabilities in conjunction with the scaled values of collisional rate coefficients are used in the Sobolev Large Velocity Gradient analysis. Out of a large number of lines, we have selected the strongest ones. In the low lying levels, besides the 4 observed lines of CH(2)CHCN, we have discussed about 8 additional transitions, of which 2 showing the phenomenon of anomalous absorption and 6 showing emission feature are found. These lines may play important role for the search of vinyl cyanide in a cosmic object. Elsevier 2019-08-30 /pmc/articles/PMC6726722/ /pubmed/31508529 http://dx.doi.org/10.1016/j.heliyon.2019.e02384 Text en © 2019 Published by Elsevier Ltd. http://creativecommons.org/licenses/by-nc-nd/4.0/ This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Article
Sharma, Mohit K.
Vinyl cyanide (CH(2)CHCN) in interstellar space: potential spectral lines for its detection
title Vinyl cyanide (CH(2)CHCN) in interstellar space: potential spectral lines for its detection
title_full Vinyl cyanide (CH(2)CHCN) in interstellar space: potential spectral lines for its detection
title_fullStr Vinyl cyanide (CH(2)CHCN) in interstellar space: potential spectral lines for its detection
title_full_unstemmed Vinyl cyanide (CH(2)CHCN) in interstellar space: potential spectral lines for its detection
title_short Vinyl cyanide (CH(2)CHCN) in interstellar space: potential spectral lines for its detection
title_sort vinyl cyanide (ch(2)chcn) in interstellar space: potential spectral lines for its detection
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6726722/
https://www.ncbi.nlm.nih.gov/pubmed/31508529
http://dx.doi.org/10.1016/j.heliyon.2019.e02384
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