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Regioselective trans-Carboboration of Propargyl Alcohols

[Image: see text] Proper choice of the base allowed trans-diboration of propargyl alcohols with B(2)(pin)(2) to evolve into an exquisitely regioselective procedure for net trans-carboboration. The method is modular as to the newly introduced carbon substituent (aryl, methyl, allyl, benzyl, alkynyl),...

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Detalles Bibliográficos
Autores principales: Jin, Hongming, Fürstner, Alois
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6727597/
https://www.ncbi.nlm.nih.gov/pubmed/30993987
http://dx.doi.org/10.1021/acs.orglett.9b01225