Cargando…
Regioselective trans-Carboboration of Propargyl Alcohols
[Image: see text] Proper choice of the base allowed trans-diboration of propargyl alcohols with B(2)(pin)(2) to evolve into an exquisitely regioselective procedure for net trans-carboboration. The method is modular as to the newly introduced carbon substituent (aryl, methyl, allyl, benzyl, alkynyl),...
Autores principales: | Jin, Hongming, Fürstner, Alois |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2019
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6727597/ https://www.ncbi.nlm.nih.gov/pubmed/30993987 http://dx.doi.org/10.1021/acs.orglett.9b01225 |
Ejemplares similares
-
Modular Synthesis of Furans with up to Four Different Substituents by a trans‐Carboboration Strategy
por: Jin, Hongming, et al.
Publicado: (2020) -
Regioselective trans‐Hydrostannation of Boron‐Capped Alkynes
por: Melot, Romain, et al.
Publicado: (2021) -
Divergent Elementoboration: 1,3‐Haloboration versus 1,1‐Carboboration of Propargyl Esters
por: Wilkins, Lewis C., et al.
Publicado: (2018) -
Regioselective Dihalohydration Reactions of Propargylic Alcohols: Gold-Catalyzed and Noncatalyzed Reactions**
por: D’Oyley, Jarryl M, et al.
Publicado: (2014) -
Intercepting the Gold‐Catalysed Meyer–Schuster Rearrangement by Controlled Protodemetallation: A Regioselective Hydration of Propargylic Alcohols
por: Pennell, Matthew N., et al.
Publicado: (2016)