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Electron Paramagnetic Resonance Signature of Tetragonal Low Spin Iron(V)-Nitrido and -Oxo Complexes Derived from the Electronic Structure Analysis of Heme and Non-Heme Archetypes

[Image: see text] Iron(V)-nitrido and -oxo complexes have been proposed as key intermediates in a diverse array of chemical transformations. Herein we present a detailed electronic-structure analysis of [Fe(V)(N)(TPP)] (1, TPP(2–) = tetraphenylporphyrinato), and [Fe(V)(N)(cyclam-ac)](+) (2, cyclam-a...

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Detalles Bibliográficos
Autores principales:	Chang, Hao-Ching, Mondal, Bhaskar, Fang, Huayi, Neese, Frank, Bill, Eckhard, Ye, Shengfa
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2019
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6728100/ https://www.ncbi.nlm.nih.gov/pubmed/30620571 http://dx.doi.org/10.1021/jacs.8b11429

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