Electrochemical Alkoxysulfonylation Difunctionalization of Styrene Derivatives Using Sodium Sulfinates as Sulfonyl Sources

[Image: see text] An eco-friendly method for the synthesis of β-alkoxy sulfones via electrochemical alkoxysulfonylation reaction of styrenes with sodium sulfinates as sulfonyl sources has been established. The reaction is conducted in an undivided cell at room temperature and tolerates a wide scope...

Descripción completa

Detalles Bibliográficos
Autores principales: Mei, Haibo, Liu, Jiang, Guo, Yunjie, Han, Jianlin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6733175/
https://www.ncbi.nlm.nih.gov/pubmed/31508561
http://dx.doi.org/10.1021/acsomega.9b02442
_version_ 1783449935668051968
author Mei, Haibo
Liu, Jiang
Guo, Yunjie
Han, Jianlin
author_facet Mei, Haibo
Liu, Jiang
Guo, Yunjie
Han, Jianlin
author_sort Mei, Haibo
collection PubMed
description [Image: see text] An eco-friendly method for the synthesis of β-alkoxy sulfones via electrochemical alkoxysulfonylation reaction of styrenes with sodium sulfinates as sulfonyl sources has been established. The reaction is conducted in an undivided cell at room temperature and tolerates a wide scope of styrenes, sodium sulfinates, and alcohols. The reaction does not need any chemical oxidants and transition-metal catalysts, which provides a new and green access to β-alkoxy sulfones.
format Online
Article
Text
id pubmed-6733175
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-67331752019-09-10 Electrochemical Alkoxysulfonylation Difunctionalization of Styrene Derivatives Using Sodium Sulfinates as Sulfonyl Sources Mei, Haibo Liu, Jiang Guo, Yunjie Han, Jianlin ACS Omega [Image: see text] An eco-friendly method for the synthesis of β-alkoxy sulfones via electrochemical alkoxysulfonylation reaction of styrenes with sodium sulfinates as sulfonyl sources has been established. The reaction is conducted in an undivided cell at room temperature and tolerates a wide scope of styrenes, sodium sulfinates, and alcohols. The reaction does not need any chemical oxidants and transition-metal catalysts, which provides a new and green access to β-alkoxy sulfones. American Chemical Society 2019-08-20 /pmc/articles/PMC6733175/ /pubmed/31508561 http://dx.doi.org/10.1021/acsomega.9b02442 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Mei, Haibo
Liu, Jiang
Guo, Yunjie
Han, Jianlin
Electrochemical Alkoxysulfonylation Difunctionalization of Styrene Derivatives Using Sodium Sulfinates as Sulfonyl Sources
title Electrochemical Alkoxysulfonylation Difunctionalization of Styrene Derivatives Using Sodium Sulfinates as Sulfonyl Sources
title_full Electrochemical Alkoxysulfonylation Difunctionalization of Styrene Derivatives Using Sodium Sulfinates as Sulfonyl Sources
title_fullStr Electrochemical Alkoxysulfonylation Difunctionalization of Styrene Derivatives Using Sodium Sulfinates as Sulfonyl Sources
title_full_unstemmed Electrochemical Alkoxysulfonylation Difunctionalization of Styrene Derivatives Using Sodium Sulfinates as Sulfonyl Sources
title_short Electrochemical Alkoxysulfonylation Difunctionalization of Styrene Derivatives Using Sodium Sulfinates as Sulfonyl Sources
title_sort electrochemical alkoxysulfonylation difunctionalization of styrene derivatives using sodium sulfinates as sulfonyl sources
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6733175/
https://www.ncbi.nlm.nih.gov/pubmed/31508561
http://dx.doi.org/10.1021/acsomega.9b02442
work_keys_str_mv AT meihaibo electrochemicalalkoxysulfonylationdifunctionalizationofstyrenederivativesusingsodiumsulfinatesassulfonylsources
AT liujiang electrochemicalalkoxysulfonylationdifunctionalizationofstyrenederivativesusingsodiumsulfinatesassulfonylsources
AT guoyunjie electrochemicalalkoxysulfonylationdifunctionalizationofstyrenederivativesusingsodiumsulfinatesassulfonylsources
AT hanjianlin electrochemicalalkoxysulfonylationdifunctionalizationofstyrenederivativesusingsodiumsulfinatesassulfonylsources

Ejemplares similares