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Mechanistic Features in Al(I)-Mediated Oxidative Addition of Aryl C–F Bonds: Insights From Density Functional Theory Calculations

The oxidative addition of a range of robust aryl C–F bonds to a single Al(I) center supported by a (NacNac)(−) bidentate ligand ((NacNac)(−) = [ArNC(Me)CHC(Me)NAr](−) and Ar = 2,6– [Formula: see text] C(6)H(3)) have been explored by density functional theory calculations. Our calculations demonstrat...

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Detalles Bibliográficos
Autores principales:	Zhang, Xiangfei, Li, Ping, Wang, Binju, Cao, Zexing
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Frontiers Media S.A. 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6733912/ https://www.ncbi.nlm.nih.gov/pubmed/31552218 http://dx.doi.org/10.3389/fchem.2019.00596

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