Reaction selectivity of homochiral versus heterochiral intermolecular reactions of prochiral terminal alkynes on surfaces

Controlling selectivity between homochiral and heterochiral reaction pathways on surfaces remains a great challenge. Here, competing reactions of a prochiral alkyne on Ag(111): two-dimensional (2D) homochiral Glaser coupling and heterochiral cross-coupling with a Bergman cyclization step have been e...

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Detalles Bibliográficos
Autores principales: Wang, Tao, Lv, Haifeng, Huang, Jianmin, Shan, Huan, Feng, Lin, Mao, Yahui, Wang, Jinyi, Zhang, Wenzhao, Han, Dong, Xu, Qian, Du, Pingwu, Zhao, Aidi, Wu, Xiaojun, Tait, Steven L., Zhu, Junfa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6739358/
https://www.ncbi.nlm.nih.gov/pubmed/31511503
http://dx.doi.org/10.1038/s41467-019-12102-y

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