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Redox potential changes during ATP‐dependent corrinoid reduction determined by redox titrations with europium(II)–DTPA
Corrinoids are essential cofactors of enzymes involved in the C(1) metabolism of anaerobes. The active, super‐reduced [Co(I)] state of the corrinoid cofactor is highly sensitive to autoxidation. In O‐demethylases, the oxidation to inactive [Co(II)] is reversed by an ATP‐dependent electron transfer c...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley & Sons, Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6739815/ https://www.ncbi.nlm.nih.gov/pubmed/31359509 http://dx.doi.org/10.1002/pro.3699 |