Charge-to-Spin Conversion by the Rashba–Edelstein Effect in Two-Dimensional van der Waals Heterostructures up to Room Temperature

[Image: see text] The proximity of a transition-metal dichalcogenide (TMD) to graphene imprints a rich spin texture in graphene and complements its high-quality charge/spin transport by inducing spin–orbit coupling (SOC). Rashba and valley-Zeeman SOCs are the origin of charge-to-spin conversion mechanisms such as the Rashba–Edelstein effect (REE) and spin Hall effect (SHE). In this work, we experimentally demonstrate for the first time charge-to-spin conversion due to the REE in a monolayer WS(2)-graphene van der Waals heterostructure. We measure the current-induced spin polarization up to room temperature and control it by a gate electric field. Our observation of the REE and the inverse of the effect (IREE) is accompanied by the SHE, which we discriminate by symmetry-resolved spin precession under oblique magnetic fields. These measurements also allow for the quantification of the efficiencies of charge-to-spin conversion by each of the two effects. These findings are a clear indication of induced Rashba and valley-Zeeman SOC in graphene that lead to the generation of spin accumulation and spin current without using ferromagnetic electrodes. These realizations have considerable significance for spintronic applications, providing accessible routes toward all-electrical spin generation and manipulation in two-dimensional materials.