Emergence and Applications of Base Metals (Fe, Co, and Ni) in Hydroboration and Hydrosilylation

Base metal catalysis offers an alternative to reactions, which were once dominated by precious metals in hydrofunctionalization reactions. This review article details the development of some base metals (Fe, Co, and Ni) in the hydroboration and hydrosilylation reactions concomitant with a brief over...

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Detalles Bibliográficos
Autores principales: Tamang, Sem Raj, Findlater, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6749197/
https://www.ncbi.nlm.nih.gov/pubmed/31484333
http://dx.doi.org/10.3390/molecules24173194
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author Tamang, Sem Raj
Findlater, Michael
author_facet Tamang, Sem Raj
Findlater, Michael
author_sort Tamang, Sem Raj
collection PubMed
description Base metal catalysis offers an alternative to reactions, which were once dominated by precious metals in hydrofunctionalization reactions. This review article details the development of some base metals (Fe, Co, and Ni) in the hydroboration and hydrosilylation reactions concomitant with a brief overview of recent advances in the field. Applications of both commercially available metal salts and well-defined metal complexes in catalysis and opportunities to further advance the field is discussed as well.
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spelling pubmed-67491972019-09-27 Emergence and Applications of Base Metals (Fe, Co, and Ni) in Hydroboration and Hydrosilylation Tamang, Sem Raj Findlater, Michael Molecules Review Base metal catalysis offers an alternative to reactions, which were once dominated by precious metals in hydrofunctionalization reactions. This review article details the development of some base metals (Fe, Co, and Ni) in the hydroboration and hydrosilylation reactions concomitant with a brief overview of recent advances in the field. Applications of both commercially available metal salts and well-defined metal complexes in catalysis and opportunities to further advance the field is discussed as well. MDPI 2019-09-03 /pmc/articles/PMC6749197/ /pubmed/31484333 http://dx.doi.org/10.3390/molecules24173194 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Tamang, Sem Raj
Findlater, Michael
Emergence and Applications of Base Metals (Fe, Co, and Ni) in Hydroboration and Hydrosilylation
title Emergence and Applications of Base Metals (Fe, Co, and Ni) in Hydroboration and Hydrosilylation
title_full Emergence and Applications of Base Metals (Fe, Co, and Ni) in Hydroboration and Hydrosilylation
title_fullStr Emergence and Applications of Base Metals (Fe, Co, and Ni) in Hydroboration and Hydrosilylation
title_full_unstemmed Emergence and Applications of Base Metals (Fe, Co, and Ni) in Hydroboration and Hydrosilylation
title_short Emergence and Applications of Base Metals (Fe, Co, and Ni) in Hydroboration and Hydrosilylation
title_sort emergence and applications of base metals (fe, co, and ni) in hydroboration and hydrosilylation
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6749197/
https://www.ncbi.nlm.nih.gov/pubmed/31484333
http://dx.doi.org/10.3390/molecules24173194
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