A Green Water-Soluble Cyclophosphazene as a Flame Retardant Finish for Textiles

Poly- and cyclophosphazenes are excellent flame retardants but currently, are not used as textile finishing agents because water-soluble and permanent washing systems are missing. Here, we demonstrate for the first time, the successful usage of a water-soluble cyclotriphosphazene derivative for text...

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Autores principales: Mayer-Gall, Thomas, Plohl, Dennis, Derksen, Leonie, Lauer, Dana, Neldner, Pia, Ali, Wael, Fuchs, Sabine, Gutmann, Jochen S., Opwis, Klaus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6749382/
https://www.ncbi.nlm.nih.gov/pubmed/31455031
http://dx.doi.org/10.3390/molecules24173100
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author Mayer-Gall, Thomas
Plohl, Dennis
Derksen, Leonie
Lauer, Dana
Neldner, Pia
Ali, Wael
Fuchs, Sabine
Gutmann, Jochen S.
Opwis, Klaus
author_facet Mayer-Gall, Thomas
Plohl, Dennis
Derksen, Leonie
Lauer, Dana
Neldner, Pia
Ali, Wael
Fuchs, Sabine
Gutmann, Jochen S.
Opwis, Klaus
author_sort Mayer-Gall, Thomas
collection PubMed
description Poly- and cyclophosphazenes are excellent flame retardants but currently, are not used as textile finishing agents because water-soluble and permanent washing systems are missing. Here, we demonstrate for the first time, the successful usage of a water-soluble cyclotriphosphazene derivative for textile finishing for cotton, different cotton/polyester, and cotton/polyamide blend fabrics. A durable finish was achieved using a photoinduced grafting reaction. The flame retardant properties of the various fabrics were improved with a higher limiting oxygen index, a reduced heat release rate, and an exhibition of intumescent. Furthermore, the finished textiles passed several standardized flammability tests.
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spelling pubmed-67493822019-09-27 A Green Water-Soluble Cyclophosphazene as a Flame Retardant Finish for Textiles Mayer-Gall, Thomas Plohl, Dennis Derksen, Leonie Lauer, Dana Neldner, Pia Ali, Wael Fuchs, Sabine Gutmann, Jochen S. Opwis, Klaus Molecules Article Poly- and cyclophosphazenes are excellent flame retardants but currently, are not used as textile finishing agents because water-soluble and permanent washing systems are missing. Here, we demonstrate for the first time, the successful usage of a water-soluble cyclotriphosphazene derivative for textile finishing for cotton, different cotton/polyester, and cotton/polyamide blend fabrics. A durable finish was achieved using a photoinduced grafting reaction. The flame retardant properties of the various fabrics were improved with a higher limiting oxygen index, a reduced heat release rate, and an exhibition of intumescent. Furthermore, the finished textiles passed several standardized flammability tests. MDPI 2019-08-26 /pmc/articles/PMC6749382/ /pubmed/31455031 http://dx.doi.org/10.3390/molecules24173100 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Mayer-Gall, Thomas
Plohl, Dennis
Derksen, Leonie
Lauer, Dana
Neldner, Pia
Ali, Wael
Fuchs, Sabine
Gutmann, Jochen S.
Opwis, Klaus
A Green Water-Soluble Cyclophosphazene as a Flame Retardant Finish for Textiles
title A Green Water-Soluble Cyclophosphazene as a Flame Retardant Finish for Textiles
title_full A Green Water-Soluble Cyclophosphazene as a Flame Retardant Finish for Textiles
title_fullStr A Green Water-Soluble Cyclophosphazene as a Flame Retardant Finish for Textiles
title_full_unstemmed A Green Water-Soluble Cyclophosphazene as a Flame Retardant Finish for Textiles
title_short A Green Water-Soluble Cyclophosphazene as a Flame Retardant Finish for Textiles
title_sort green water-soluble cyclophosphazene as a flame retardant finish for textiles
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6749382/
https://www.ncbi.nlm.nih.gov/pubmed/31455031
http://dx.doi.org/10.3390/molecules24173100
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