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Magnesium(II) d-Gluconate Complexes Relevant to Radioactive Waste Disposals: Metal-Ion-Induced Ligand Deprotonation or Ligand-Promoted Metal-Ion Hydrolysis?
[Image: see text] The complexation equilibria between Mg(2+) and d-gluconate (Gluc(–)) ions are of particular importance in modeling the chemical speciation in low- and intermediate-level radioactive waste repositories. NMR measurements and potentiometric titrations conducted at 25 °C and 4 M ionic...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2019
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6750863/ https://www.ncbi.nlm.nih.gov/pubmed/31066555 http://dx.doi.org/10.1021/acs.inorgchem.9b00289 |