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Spectroscopic Description of the E(1) State of Mo Nitrogenase Based on Mo and Fe X-ray Absorption and Mössbauer Studies

[Image: see text] Mo nitrogenase (N2ase) utilizes a two-component protein system, the catalytic MoFe and its electron-transfer partner FeP, to reduce atmospheric dinitrogen (N(2)) to ammonia (NH(3)). The FeMo cofactor contained in the MoFe protein serves as the catalytic center for this reaction and...

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Detalles Bibliográficos
Autores principales: Van Stappen, Casey, Davydov, Roman, Yang, Zhi-Yong, Fan, Ruixi, Guo, Yisong, Bill, Eckhard, Seefeldt, Lance C., Hoffman, Brian M., DeBeer, Serena
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6751781/
https://www.ncbi.nlm.nih.gov/pubmed/31441651
http://dx.doi.org/10.1021/acs.inorgchem.9b01951