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Temperature Controls Guest Uptake and Release from Zn(4)L(4) Tetrahedra

[Image: see text] We report the preparation of triazatruxene-faced tetrahedral cage 1, which exhibits two diastereomeric configurations (T1 and T2) that differ in the handedness of the ligand faces relative to that of the octahedrally coordinated metal centers. At lower temperatures, T1 is favored,...

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Detalles Bibliográficos
Autores principales: Zhang, Dawei, Ronson, Tanya K., Güryel, Songül, Thoburn, John D., Wales, David J., Nitschke, Jonathan R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6753657/
https://www.ncbi.nlm.nih.gov/pubmed/31478658
http://dx.doi.org/10.1021/jacs.9b07307

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