Cargando…

1,2,3-Triazolium macrocycles in supramolecular chemistry

In this short review, we describe different pathways for synthesizing 1,2,3-triazolium macrocycles and focus on their application in different areas of supramolecular chemistry. The synthesis is mostly relying on the well-known “click reaction” (CuAAC) leading to 1,4-disubstituted 1,2,3-triazoles th...

Descripción completa

Detalles Bibliográficos
Autores principales: Safarnejad Shad, Mastaneh, Santhini, Pulikkal Veettil, Dehaen, Wim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6753851/
https://www.ncbi.nlm.nih.gov/pubmed/31579083
http://dx.doi.org/10.3762/bjoc.15.211
Descripción
Sumario:In this short review, we describe different pathways for synthesizing 1,2,3-triazolium macrocycles and focus on their application in different areas of supramolecular chemistry. The synthesis is mostly relying on the well-known “click reaction” (CuAAC) leading to 1,4-disubstituted 1,2,3-triazoles that then can be quaternized. Applications of triazolium macrocycles thus prepared include receptors for molecular recognition of anionic species, pH sensors, mechanically interlocked molecules, molecular machines, and molecular reactors.