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Synthesis and Kinetics of the N-(2-Methyl-6-ethyl phenyl)-1-methoxypropyl-2-imine Schiff Base Catalyzed by NKC-9 Cation Exchange Resin

[Image: see text] The kinetics of condensation reaction of methoxyacetone with 2-methyl-6-ethyl aniline catalyzed by NKC-9 cation exchange resin was studied for the first time. The reaction temperature of Schiff base synthesis was determined in the range of 367.15 to 401.15 K by the batch experiment...

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Autores principales: Chen, Jian, Pang, Chong, Zhang, Mao Sheng, Che, Yuan Yuan, Zhao, Qi Mang, Zhu, Meng Jing, Xiang, Fu Wei, Chang, Gang Gang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6756530/
https://www.ncbi.nlm.nih.gov/pubmed/31552313
http://dx.doi.org/10.1021/acsomega.9b01197
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author Chen, Jian
Pang, Chong
Zhang, Mao Sheng
Che, Yuan Yuan
Zhao, Qi Mang
Zhu, Meng Jing
Xiang, Fu Wei
Chang, Gang Gang
author_facet Chen, Jian
Pang, Chong
Zhang, Mao Sheng
Che, Yuan Yuan
Zhao, Qi Mang
Zhu, Meng Jing
Xiang, Fu Wei
Chang, Gang Gang
author_sort Chen, Jian
collection PubMed
description [Image: see text] The kinetics of condensation reaction of methoxyacetone with 2-methyl-6-ethyl aniline catalyzed by NKC-9 cation exchange resin was studied for the first time. The reaction temperature of Schiff base synthesis was determined in the range of 367.15 to 401.15 K by the batch experiments, and influences of reactant molar ratio, temperature, catalyst dosage, and particle size on the ultimate conversion were also studied. The dynamic data were used to be relevant with PH, ER(1), ER(2), and Langmuir Hinshelwood Hougen Watson homogeneity models. Model parameters, including reaction equilibrium constants, activation energy, enthalpy change, entropy change, and rate constants, were solved. The accuracy of the model was validated by means of both experimental proofs and standard deviation between the predicted and experimental data. Finally, a series of characterization tests such as Fourier transform infrared spectroscopy, X-ray diffraction, and polarizing microscopy were performed to investigate the structure and properties of NKC-9.
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spelling pubmed-67565302019-09-24 Synthesis and Kinetics of the N-(2-Methyl-6-ethyl phenyl)-1-methoxypropyl-2-imine Schiff Base Catalyzed by NKC-9 Cation Exchange Resin Chen, Jian Pang, Chong Zhang, Mao Sheng Che, Yuan Yuan Zhao, Qi Mang Zhu, Meng Jing Xiang, Fu Wei Chang, Gang Gang ACS Omega [Image: see text] The kinetics of condensation reaction of methoxyacetone with 2-methyl-6-ethyl aniline catalyzed by NKC-9 cation exchange resin was studied for the first time. The reaction temperature of Schiff base synthesis was determined in the range of 367.15 to 401.15 K by the batch experiments, and influences of reactant molar ratio, temperature, catalyst dosage, and particle size on the ultimate conversion were also studied. The dynamic data were used to be relevant with PH, ER(1), ER(2), and Langmuir Hinshelwood Hougen Watson homogeneity models. Model parameters, including reaction equilibrium constants, activation energy, enthalpy change, entropy change, and rate constants, were solved. The accuracy of the model was validated by means of both experimental proofs and standard deviation between the predicted and experimental data. Finally, a series of characterization tests such as Fourier transform infrared spectroscopy, X-ray diffraction, and polarizing microscopy were performed to investigate the structure and properties of NKC-9. American Chemical Society 2019-09-05 /pmc/articles/PMC6756530/ /pubmed/31552313 http://dx.doi.org/10.1021/acsomega.9b01197 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Chen, Jian
Pang, Chong
Zhang, Mao Sheng
Che, Yuan Yuan
Zhao, Qi Mang
Zhu, Meng Jing
Xiang, Fu Wei
Chang, Gang Gang
Synthesis and Kinetics of the N-(2-Methyl-6-ethyl phenyl)-1-methoxypropyl-2-imine Schiff Base Catalyzed by NKC-9 Cation Exchange Resin
title Synthesis and Kinetics of the N-(2-Methyl-6-ethyl phenyl)-1-methoxypropyl-2-imine Schiff Base Catalyzed by NKC-9 Cation Exchange Resin
title_full Synthesis and Kinetics of the N-(2-Methyl-6-ethyl phenyl)-1-methoxypropyl-2-imine Schiff Base Catalyzed by NKC-9 Cation Exchange Resin
title_fullStr Synthesis and Kinetics of the N-(2-Methyl-6-ethyl phenyl)-1-methoxypropyl-2-imine Schiff Base Catalyzed by NKC-9 Cation Exchange Resin
title_full_unstemmed Synthesis and Kinetics of the N-(2-Methyl-6-ethyl phenyl)-1-methoxypropyl-2-imine Schiff Base Catalyzed by NKC-9 Cation Exchange Resin
title_short Synthesis and Kinetics of the N-(2-Methyl-6-ethyl phenyl)-1-methoxypropyl-2-imine Schiff Base Catalyzed by NKC-9 Cation Exchange Resin
title_sort synthesis and kinetics of the n-(2-methyl-6-ethyl phenyl)-1-methoxypropyl-2-imine schiff base catalyzed by nkc-9 cation exchange resin
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6756530/
https://www.ncbi.nlm.nih.gov/pubmed/31552313
http://dx.doi.org/10.1021/acsomega.9b01197
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