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Synthesis and Kinetics of the N-(2-Methyl-6-ethyl phenyl)-1-methoxypropyl-2-imine Schiff Base Catalyzed by NKC-9 Cation Exchange Resin
[Image: see text] The kinetics of condensation reaction of methoxyacetone with 2-methyl-6-ethyl aniline catalyzed by NKC-9 cation exchange resin was studied for the first time. The reaction temperature of Schiff base synthesis was determined in the range of 367.15 to 401.15 K by the batch experiment...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2019
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6756530/ https://www.ncbi.nlm.nih.gov/pubmed/31552313 http://dx.doi.org/10.1021/acsomega.9b01197 |
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author | Chen, Jian Pang, Chong Zhang, Mao Sheng Che, Yuan Yuan Zhao, Qi Mang Zhu, Meng Jing Xiang, Fu Wei Chang, Gang Gang |
author_facet | Chen, Jian Pang, Chong Zhang, Mao Sheng Che, Yuan Yuan Zhao, Qi Mang Zhu, Meng Jing Xiang, Fu Wei Chang, Gang Gang |
author_sort | Chen, Jian |
collection | PubMed |
description | [Image: see text] The kinetics of condensation reaction of methoxyacetone with 2-methyl-6-ethyl aniline catalyzed by NKC-9 cation exchange resin was studied for the first time. The reaction temperature of Schiff base synthesis was determined in the range of 367.15 to 401.15 K by the batch experiments, and influences of reactant molar ratio, temperature, catalyst dosage, and particle size on the ultimate conversion were also studied. The dynamic data were used to be relevant with PH, ER(1), ER(2), and Langmuir Hinshelwood Hougen Watson homogeneity models. Model parameters, including reaction equilibrium constants, activation energy, enthalpy change, entropy change, and rate constants, were solved. The accuracy of the model was validated by means of both experimental proofs and standard deviation between the predicted and experimental data. Finally, a series of characterization tests such as Fourier transform infrared spectroscopy, X-ray diffraction, and polarizing microscopy were performed to investigate the structure and properties of NKC-9. |
format | Online Article Text |
id | pubmed-6756530 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-67565302019-09-24 Synthesis and Kinetics of the N-(2-Methyl-6-ethyl phenyl)-1-methoxypropyl-2-imine Schiff Base Catalyzed by NKC-9 Cation Exchange Resin Chen, Jian Pang, Chong Zhang, Mao Sheng Che, Yuan Yuan Zhao, Qi Mang Zhu, Meng Jing Xiang, Fu Wei Chang, Gang Gang ACS Omega [Image: see text] The kinetics of condensation reaction of methoxyacetone with 2-methyl-6-ethyl aniline catalyzed by NKC-9 cation exchange resin was studied for the first time. The reaction temperature of Schiff base synthesis was determined in the range of 367.15 to 401.15 K by the batch experiments, and influences of reactant molar ratio, temperature, catalyst dosage, and particle size on the ultimate conversion were also studied. The dynamic data were used to be relevant with PH, ER(1), ER(2), and Langmuir Hinshelwood Hougen Watson homogeneity models. Model parameters, including reaction equilibrium constants, activation energy, enthalpy change, entropy change, and rate constants, were solved. The accuracy of the model was validated by means of both experimental proofs and standard deviation between the predicted and experimental data. Finally, a series of characterization tests such as Fourier transform infrared spectroscopy, X-ray diffraction, and polarizing microscopy were performed to investigate the structure and properties of NKC-9. American Chemical Society 2019-09-05 /pmc/articles/PMC6756530/ /pubmed/31552313 http://dx.doi.org/10.1021/acsomega.9b01197 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes. |
spellingShingle | Chen, Jian Pang, Chong Zhang, Mao Sheng Che, Yuan Yuan Zhao, Qi Mang Zhu, Meng Jing Xiang, Fu Wei Chang, Gang Gang Synthesis and Kinetics of the N-(2-Methyl-6-ethyl phenyl)-1-methoxypropyl-2-imine Schiff Base Catalyzed by NKC-9 Cation Exchange Resin |
title | Synthesis and Kinetics of
the N-(2-Methyl-6-ethyl
phenyl)-1-methoxypropyl-2-imine Schiff Base Catalyzed by NKC-9
Cation Exchange Resin |
title_full | Synthesis and Kinetics of
the N-(2-Methyl-6-ethyl
phenyl)-1-methoxypropyl-2-imine Schiff Base Catalyzed by NKC-9
Cation Exchange Resin |
title_fullStr | Synthesis and Kinetics of
the N-(2-Methyl-6-ethyl
phenyl)-1-methoxypropyl-2-imine Schiff Base Catalyzed by NKC-9
Cation Exchange Resin |
title_full_unstemmed | Synthesis and Kinetics of
the N-(2-Methyl-6-ethyl
phenyl)-1-methoxypropyl-2-imine Schiff Base Catalyzed by NKC-9
Cation Exchange Resin |
title_short | Synthesis and Kinetics of
the N-(2-Methyl-6-ethyl
phenyl)-1-methoxypropyl-2-imine Schiff Base Catalyzed by NKC-9
Cation Exchange Resin |
title_sort | synthesis and kinetics of
the n-(2-methyl-6-ethyl
phenyl)-1-methoxypropyl-2-imine schiff base catalyzed by nkc-9
cation exchange resin |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6756530/ https://www.ncbi.nlm.nih.gov/pubmed/31552313 http://dx.doi.org/10.1021/acsomega.9b01197 |
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