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From d- to l-Monosaccharide Derivatives via Photodecarboxylation–Alkylation
[Image: see text] Photodecarboxylation–alkylation of conformationally locked monosaccharides leads to inversion of stereochemistry at C5. This allows the synthesis of l-sugars from their readily available d-counterparts. Via this strategy, methyl l-guloside was synthesized from methyl d-mannoside in...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6759743/ https://www.ncbi.nlm.nih.gov/pubmed/31512472 http://dx.doi.org/10.1021/acs.orglett.9b03016 |