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A K(+)-promoted Diels–Alder reaction by using a self-assembled macrocyclic boronic ester containing two crown ether moieties
A K(+)-promoted Diels–Alder reaction of 1,4,9,10-anthradiquinone with various dienes is achieved in the presence of a self-assembled macrocyclic boronic ester [2+2](crown) containing two crown ether moieties. The reaction rate is remarkably accelerated (up to 206-fold) compared to that in the absenc...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6761878/ https://www.ncbi.nlm.nih.gov/pubmed/31588314 http://dx.doi.org/10.1039/c9sc01597c |