Spin-crossover modulation via single-crystal to single-crystal photochemical [2 + 2] reaction in Hofmann-type frameworks

This study reports the first modulation of spin-crossover (SCO) behavior via a photochemical [2 + 2] cycloaddition reaction. Here we construct two no-solvent Fe(ii)–Ag(i) bimetallic Hofmann-type frameworks, [Fe(4-spy)(2){Ag(CN)(2)}(2)] (1) and [Fe(2,4-bpe)(2){Ag(CN)(2)}(2)] (2) (4-spy = 4-styrylpyri...

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Detalles Bibliográficos
Autores principales: Wang, Long-Fei, Zhuang, Wei-Man, Huang, Guo-Zhang, Chen, Yan-Cong, Qiu, Jiang-Zhen, Ni, Zhao-Ping, Tong, Ming-Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6764279/
https://www.ncbi.nlm.nih.gov/pubmed/31588302
http://dx.doi.org/10.1039/c9sc02274k

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