Fluorine-Substituted Arylphosphine for an NHC-Ni(I) System, Air-Stable in a Solid State but Catalytically Active in Solution

Monovalent NHC-nickel complexes bearing triarylphosphine, in which fluorine is incorporated onto the aryl groups, have been synthesized. Tris(3,5-di(trifluoromethyl)-phenyl)phosphine efficiently gave a monovalent nickel bromide complex, whose structure was determined by X-ray diffraction analysis fo...

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Detalles Bibliográficos
Autores principales: Matsubara, Kouki, Fujii, Takahiro, Hosokawa, Rion, Inatomi, Takahiro, Yamada, Yuji, Koga, Yuji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6766797/
https://www.ncbi.nlm.nih.gov/pubmed/31487944
http://dx.doi.org/10.3390/molecules24183222

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6766797/
https://www.ncbi.nlm.nih.gov/pubmed/31487944
http://dx.doi.org/10.3390/molecules24183222

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