Porphyrin Supramolecular Arrays Formed by Weakly Interacting Meso-Functional Groups on Au(111)

The formation of a binary porphyrinic self-assembled system between meso-tetrakis(4-carboxyphenyl) porphyrin (TCPP) and meso-tetrakis(4-dimethyl amino) porphyrin (TDAP) was easily designed through non-covalent interactions in solution and adsorbed on a gold substrate. It was found that non-covalent...

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Autores principales: Sánchez-Muñoz, Esteban, Gárate-Morales, José L., Sandoval-Lira, Jacinto, Hernández-Pérez, Julio M., Aguilar-Sánchez, Rocío
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6766800/
https://www.ncbi.nlm.nih.gov/pubmed/31547376
http://dx.doi.org/10.3390/molecules24183326
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author Sánchez-Muñoz, Esteban
Gárate-Morales, José L.
Sandoval-Lira, Jacinto
Hernández-Pérez, Julio M.
Aguilar-Sánchez, Rocío
author_facet Sánchez-Muñoz, Esteban
Gárate-Morales, José L.
Sandoval-Lira, Jacinto
Hernández-Pérez, Julio M.
Aguilar-Sánchez, Rocío
author_sort Sánchez-Muñoz, Esteban
collection PubMed
description The formation of a binary porphyrinic self-assembled system between meso-tetrakis(4-carboxyphenyl) porphyrin (TCPP) and meso-tetrakis(4-dimethyl amino) porphyrin (TDAP) was easily designed through non-covalent interactions in solution and adsorbed on a gold substrate. It was found that non-covalent interactions and geometrical conformations between porphyrins allow their self-assembly into a well-defined arrangement, which was confirmed by UV-Vis spectroscopy, electrochemistry, atomic force microscopy and density functional theory (DFT) studies.
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spelling pubmed-67668002019-10-02 Porphyrin Supramolecular Arrays Formed by Weakly Interacting Meso-Functional Groups on Au(111) Sánchez-Muñoz, Esteban Gárate-Morales, José L. Sandoval-Lira, Jacinto Hernández-Pérez, Julio M. Aguilar-Sánchez, Rocío Molecules Article The formation of a binary porphyrinic self-assembled system between meso-tetrakis(4-carboxyphenyl) porphyrin (TCPP) and meso-tetrakis(4-dimethyl amino) porphyrin (TDAP) was easily designed through non-covalent interactions in solution and adsorbed on a gold substrate. It was found that non-covalent interactions and geometrical conformations between porphyrins allow their self-assembly into a well-defined arrangement, which was confirmed by UV-Vis spectroscopy, electrochemistry, atomic force microscopy and density functional theory (DFT) studies. MDPI 2019-09-12 /pmc/articles/PMC6766800/ /pubmed/31547376 http://dx.doi.org/10.3390/molecules24183326 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Sánchez-Muñoz, Esteban
Gárate-Morales, José L.
Sandoval-Lira, Jacinto
Hernández-Pérez, Julio M.
Aguilar-Sánchez, Rocío
Porphyrin Supramolecular Arrays Formed by Weakly Interacting Meso-Functional Groups on Au(111)
title Porphyrin Supramolecular Arrays Formed by Weakly Interacting Meso-Functional Groups on Au(111)
title_full Porphyrin Supramolecular Arrays Formed by Weakly Interacting Meso-Functional Groups on Au(111)
title_fullStr Porphyrin Supramolecular Arrays Formed by Weakly Interacting Meso-Functional Groups on Au(111)
title_full_unstemmed Porphyrin Supramolecular Arrays Formed by Weakly Interacting Meso-Functional Groups on Au(111)
title_short Porphyrin Supramolecular Arrays Formed by Weakly Interacting Meso-Functional Groups on Au(111)
title_sort porphyrin supramolecular arrays formed by weakly interacting meso-functional groups on au(111)
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6766800/
https://www.ncbi.nlm.nih.gov/pubmed/31547376
http://dx.doi.org/10.3390/molecules24183326
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