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A Novel One-Dimensional Porphyrin-Based Covalent Organic Framework

A novel one-dimensional covalent organic framework (COF-K) was firstly designed and synthesized through a Schiff-based reaction from a porphyrin building block and a nonlinear right-angle building block. The COF-K exhibited high BET surface area and narrow pore size of 1.25 nm and gave a CO(2) adsor...

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Detalles Bibliográficos
Autores principales: Zhang, Miao, Zheng, Ruijin, Ma, Ying, Chen, Ruiping, Sun, Xun, Sun, Xuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6767199/
https://www.ncbi.nlm.nih.gov/pubmed/31527413
http://dx.doi.org/10.3390/molecules24183361
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author Zhang, Miao
Zheng, Ruijin
Ma, Ying
Chen, Ruiping
Sun, Xun
Sun, Xuan
author_facet Zhang, Miao
Zheng, Ruijin
Ma, Ying
Chen, Ruiping
Sun, Xun
Sun, Xuan
author_sort Zhang, Miao
collection PubMed
description A novel one-dimensional covalent organic framework (COF-K) was firstly designed and synthesized through a Schiff-based reaction from a porphyrin building block and a nonlinear right-angle building block. The COF-K exhibited high BET surface area and narrow pore size of 1.25 nm and gave a CO(2) adsorption capacity of 89 mg g(−1) at 273K and 1bar.
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spelling pubmed-67671992019-10-02 A Novel One-Dimensional Porphyrin-Based Covalent Organic Framework Zhang, Miao Zheng, Ruijin Ma, Ying Chen, Ruiping Sun, Xun Sun, Xuan Molecules Communication A novel one-dimensional covalent organic framework (COF-K) was firstly designed and synthesized through a Schiff-based reaction from a porphyrin building block and a nonlinear right-angle building block. The COF-K exhibited high BET surface area and narrow pore size of 1.25 nm and gave a CO(2) adsorption capacity of 89 mg g(−1) at 273K and 1bar. MDPI 2019-09-16 /pmc/articles/PMC6767199/ /pubmed/31527413 http://dx.doi.org/10.3390/molecules24183361 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Zhang, Miao
Zheng, Ruijin
Ma, Ying
Chen, Ruiping
Sun, Xun
Sun, Xuan
A Novel One-Dimensional Porphyrin-Based Covalent Organic Framework
title A Novel One-Dimensional Porphyrin-Based Covalent Organic Framework
title_full A Novel One-Dimensional Porphyrin-Based Covalent Organic Framework
title_fullStr A Novel One-Dimensional Porphyrin-Based Covalent Organic Framework
title_full_unstemmed A Novel One-Dimensional Porphyrin-Based Covalent Organic Framework
title_short A Novel One-Dimensional Porphyrin-Based Covalent Organic Framework
title_sort novel one-dimensional porphyrin-based covalent organic framework
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6767199/
https://www.ncbi.nlm.nih.gov/pubmed/31527413
http://dx.doi.org/10.3390/molecules24183361
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