Bis‐[3]Ferrocenophanes with Central >E−E’< Bonds (E, E’=P, SiH): Preparation, Properties, and Thermal Activation

A series of bis‐[3]ferrocenophanes of the general type Fe(C(5)H(4)E’)(2)E−E(E'C(5)H(4))(2)Fe (E=P, SiH and E’=PtBu, NneoPentyl, NSi(CH(3))(3)) with an isolobal molecular framework have been prepared and characterized by heteronuclear NMR spectroscopy and X‐ray crystallography. The thermal disso...

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Detalles Bibliográficos
Autores principales: Isenberg, Stefan, Weller, Stefan, Kargin, Denis, Valić, Srećko, Schwederski, Brigitte, Kelemen, Zsolt, Bruhn, Clemens, Krekić, Kristijan, Maurer, Martin, Feil, Christoph M., Nieger, Martin, Gudat, Dietrich, Nyulászi, László, Pietschnig, Rudolf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6769432/
https://www.ncbi.nlm.nih.gov/pubmed/31592068
http://dx.doi.org/10.1002/open.201900182
Descripción
Sumario:A series of bis‐[3]ferrocenophanes of the general type Fe(C(5)H(4)E’)(2)E−E(E'C(5)H(4))(2)Fe (E=P, SiH and E’=PtBu, NneoPentyl, NSi(CH(3))(3)) with an isolobal molecular framework have been prepared and characterized by heteronuclear NMR spectroscopy and X‐ray crystallography. The thermal dissociation behavior with respect to homolytic fission of the central bond generating phosphorus centered radicals was investigated using EPR spectroscopy and quantum chemical calculations.

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