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Bis‐[3]Ferrocenophanes with Central >E−E’< Bonds (E, E’=P, SiH): Preparation, Properties, and Thermal Activation
A series of bis‐[3]ferrocenophanes of the general type Fe(C(5)H(4)E’)(2)E−E(E'C(5)H(4))(2)Fe (E=P, SiH and E’=PtBu, NneoPentyl, NSi(CH(3))(3)) with an isolobal molecular framework have been prepared and characterized by heteronuclear NMR spectroscopy and X‐ray crystallography. The thermal disso...
| Autores principales: | , , , , , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6769432/ https://www.ncbi.nlm.nih.gov/pubmed/31592068 http://dx.doi.org/10.1002/open.201900182 |
| _version_ | 1783455235663986688 |
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| author | Isenberg, Stefan Weller, Stefan Kargin, Denis Valić, Srećko Schwederski, Brigitte Kelemen, Zsolt Bruhn, Clemens Krekić, Kristijan Maurer, Martin Feil, Christoph M. Nieger, Martin Gudat, Dietrich Nyulászi, László Pietschnig, Rudolf |
| author_facet | Isenberg, Stefan Weller, Stefan Kargin, Denis Valić, Srećko Schwederski, Brigitte Kelemen, Zsolt Bruhn, Clemens Krekić, Kristijan Maurer, Martin Feil, Christoph M. Nieger, Martin Gudat, Dietrich Nyulászi, László Pietschnig, Rudolf |
| author_sort | Isenberg, Stefan |
| collection | PubMed |
| description | A series of bis‐[3]ferrocenophanes of the general type Fe(C(5)H(4)E’)(2)E−E(E'C(5)H(4))(2)Fe (E=P, SiH and E’=PtBu, NneoPentyl, NSi(CH(3))(3)) with an isolobal molecular framework have been prepared and characterized by heteronuclear NMR spectroscopy and X‐ray crystallography. The thermal dissociation behavior with respect to homolytic fission of the central bond generating phosphorus centered radicals was investigated using EPR spectroscopy and quantum chemical calculations. |
| format | Online Article Text |
| id | pubmed-6769432 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2019 |
| publisher | John Wiley and Sons Inc. |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-67694322019-10-07 Bis‐[3]Ferrocenophanes with Central >E−E’< Bonds (E, E’=P, SiH): Preparation, Properties, and Thermal Activation Isenberg, Stefan Weller, Stefan Kargin, Denis Valić, Srećko Schwederski, Brigitte Kelemen, Zsolt Bruhn, Clemens Krekić, Kristijan Maurer, Martin Feil, Christoph M. Nieger, Martin Gudat, Dietrich Nyulászi, László Pietschnig, Rudolf ChemistryOpen Full Papers A series of bis‐[3]ferrocenophanes of the general type Fe(C(5)H(4)E’)(2)E−E(E'C(5)H(4))(2)Fe (E=P, SiH and E’=PtBu, NneoPentyl, NSi(CH(3))(3)) with an isolobal molecular framework have been prepared and characterized by heteronuclear NMR spectroscopy and X‐ray crystallography. The thermal dissociation behavior with respect to homolytic fission of the central bond generating phosphorus centered radicals was investigated using EPR spectroscopy and quantum chemical calculations. John Wiley and Sons Inc. 2019-06-26 /pmc/articles/PMC6769432/ /pubmed/31592068 http://dx.doi.org/10.1002/open.201900182 Text en © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
| spellingShingle | Full Papers Isenberg, Stefan Weller, Stefan Kargin, Denis Valić, Srećko Schwederski, Brigitte Kelemen, Zsolt Bruhn, Clemens Krekić, Kristijan Maurer, Martin Feil, Christoph M. Nieger, Martin Gudat, Dietrich Nyulászi, László Pietschnig, Rudolf Bis‐[3]Ferrocenophanes with Central >E−E’< Bonds (E, E’=P, SiH): Preparation, Properties, and Thermal Activation |
| title | Bis‐[3]Ferrocenophanes with Central >E−E’< Bonds (E, E’=P, SiH): Preparation, Properties, and Thermal Activation |
| title_full | Bis‐[3]Ferrocenophanes with Central >E−E’< Bonds (E, E’=P, SiH): Preparation, Properties, and Thermal Activation |
| title_fullStr | Bis‐[3]Ferrocenophanes with Central >E−E’< Bonds (E, E’=P, SiH): Preparation, Properties, and Thermal Activation |
| title_full_unstemmed | Bis‐[3]Ferrocenophanes with Central >E−E’< Bonds (E, E’=P, SiH): Preparation, Properties, and Thermal Activation |
| title_short | Bis‐[3]Ferrocenophanes with Central >E−E’< Bonds (E, E’=P, SiH): Preparation, Properties, and Thermal Activation |
| title_sort | bis‐[3]ferrocenophanes with central >e−e’< bonds (e, e’=p, sih): preparation, properties, and thermal activation |
| topic | Full Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6769432/ https://www.ncbi.nlm.nih.gov/pubmed/31592068 http://dx.doi.org/10.1002/open.201900182 |
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