Benchmarking of Halogen Bond Strength in Solution with Nickel Fluorides: Bromine versus Iodine and Perfluoroaryl versus Perfluoroalkyl Donors

The energetics of halogen bond formation in solution have been investigated for a series of nickel fluoride halogen bond acceptors; trans‐[NiF(2‐C(5)NF(4))(PEt(3))(2)] (A1), trans‐[NiF{2‐C(5)NF(3)(4‐H)}(PEt(3))(2)] (A2), trans‐[NiF{2‐C(5)NF(3)(4‐NMe(2))}(PEt(3))(2)] (A3) and trans‐[NiF{2‐C(5)NF(2)H(...

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Detalles Bibliográficos
Autores principales: Pike, Sarah J., Hunter, Christopher A., Brammer, Lee, Perutz, Robin N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771525/
https://www.ncbi.nlm.nih.gov/pubmed/30985028
http://dx.doi.org/10.1002/chem.201900924

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771525/
https://www.ncbi.nlm.nih.gov/pubmed/30985028
http://dx.doi.org/10.1002/chem.201900924

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