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Benchmarking of Halogen Bond Strength in Solution with Nickel Fluorides: Bromine versus Iodine and Perfluoroaryl versus Perfluoroalkyl Donors
The energetics of halogen bond formation in solution have been investigated for a series of nickel fluoride halogen bond acceptors; trans‐[NiF(2‐C(5)NF(4))(PEt(3))(2)] (A1), trans‐[NiF{2‐C(5)NF(3)(4‐H)}(PEt(3))(2)] (A2), trans‐[NiF{2‐C(5)NF(3)(4‐NMe(2))}(PEt(3))(2)] (A3) and trans‐[NiF{2‐C(5)NF(2)H(...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771525/ https://www.ncbi.nlm.nih.gov/pubmed/30985028 http://dx.doi.org/10.1002/chem.201900924 |