Intramolecular Ring‐Expansion Reaction (RER) and Intermolecular Coordination of In Situ Generated Cyclic (Amino)(aryl)carbenes (cAArCs)

Cyclic (amino)(aryl)carbenes (cAArCs) based on the isoindoline core were successfully generated in situ by α‐elimination of 3‐alkoxyisoindolines at high temperatures or by deprotonation of isoindol‐2‐ium chlorides with sodium or copper(I) acetates at low temperatures. 3‐Alkoxy‐isoindolines 2 a,b‐OR...

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Detalles Bibliográficos
Autores principales: Lorkowski, Jan, Krahfuß, Mirjam, Kubicki, Maciej, Radius, Udo, Pietraszuk, Cezary
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771577/
https://www.ncbi.nlm.nih.gov/pubmed/31276243
http://dx.doi.org/10.1002/chem.201902630

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771577/
https://www.ncbi.nlm.nih.gov/pubmed/31276243
http://dx.doi.org/10.1002/chem.201902630

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