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The Nature of Hydrogen Bonds: A Delineation of the Role of Different Energy Components on Hydrogen Bond Strengths and Lengths

Hydrogen bonds are a complex interplay between different energy components, and their nature is still subject of an ongoing debate. In this minireview, we therefore provide an overview of the different perspectives on hydrogen bonding. This will be done by discussing the following individual energy...

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Detalles Bibliográficos
Autores principales: van der Lubbe, Stephanie C. C., Fonseca Guerra, Célia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771679/
https://www.ncbi.nlm.nih.gov/pubmed/31241855
http://dx.doi.org/10.1002/asia.201900717
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author van der Lubbe, Stephanie C. C.
Fonseca Guerra, Célia
author_facet van der Lubbe, Stephanie C. C.
Fonseca Guerra, Célia
author_sort van der Lubbe, Stephanie C. C.
collection PubMed
description Hydrogen bonds are a complex interplay between different energy components, and their nature is still subject of an ongoing debate. In this minireview, we therefore provide an overview of the different perspectives on hydrogen bonding. This will be done by discussing the following individual energy components: 1) electrostatic interactions, 2) charge‐transfer interactions, 3) π‐resonance assistance, 4) steric repulsion, 5) cooperative effects, 6) dispersion interactions and 7) secondary electrostatic interactions. We demonstrate how these energetic factors are essential in a correct description of the hydrogen bond, and discuss several examples of systems whose energetic and geometrical features are not captured by easy‐to‐use predictive models.
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spelling pubmed-67716792019-10-07 The Nature of Hydrogen Bonds: A Delineation of the Role of Different Energy Components on Hydrogen Bond Strengths and Lengths van der Lubbe, Stephanie C. C. Fonseca Guerra, Célia Chem Asian J Minireviews Hydrogen bonds are a complex interplay between different energy components, and their nature is still subject of an ongoing debate. In this minireview, we therefore provide an overview of the different perspectives on hydrogen bonding. This will be done by discussing the following individual energy components: 1) electrostatic interactions, 2) charge‐transfer interactions, 3) π‐resonance assistance, 4) steric repulsion, 5) cooperative effects, 6) dispersion interactions and 7) secondary electrostatic interactions. We demonstrate how these energetic factors are essential in a correct description of the hydrogen bond, and discuss several examples of systems whose energetic and geometrical features are not captured by easy‐to‐use predictive models. John Wiley and Sons Inc. 2019-07-19 2019-08-16 /pmc/articles/PMC6771679/ /pubmed/31241855 http://dx.doi.org/10.1002/asia.201900717 Text en © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Minireviews
van der Lubbe, Stephanie C. C.
Fonseca Guerra, Célia
The Nature of Hydrogen Bonds: A Delineation of the Role of Different Energy Components on Hydrogen Bond Strengths and Lengths
title The Nature of Hydrogen Bonds: A Delineation of the Role of Different Energy Components on Hydrogen Bond Strengths and Lengths
title_full The Nature of Hydrogen Bonds: A Delineation of the Role of Different Energy Components on Hydrogen Bond Strengths and Lengths
title_fullStr The Nature of Hydrogen Bonds: A Delineation of the Role of Different Energy Components on Hydrogen Bond Strengths and Lengths
title_full_unstemmed The Nature of Hydrogen Bonds: A Delineation of the Role of Different Energy Components on Hydrogen Bond Strengths and Lengths
title_short The Nature of Hydrogen Bonds: A Delineation of the Role of Different Energy Components on Hydrogen Bond Strengths and Lengths
title_sort nature of hydrogen bonds: a delineation of the role of different energy components on hydrogen bond strengths and lengths
topic Minireviews
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771679/
https://www.ncbi.nlm.nih.gov/pubmed/31241855
http://dx.doi.org/10.1002/asia.201900717
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