A General and Air‐tolerant Strategy to Conjugated Polymers within Seconds under Palladium(I) Dimer Catalysis

While current M(0)/M(II) based polymerization strategies largely focus on fine‐tuning the catalyst, reagents and conditions for each and every monomer, this report discloses a single method that allows access to a variety of different conjugated polymers within seconds at room temperature. Key to th...

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Detalles Bibliográficos
Autores principales: Magnin, Guillaume, Clifton, Jamie, Schoenebeck, Franziska
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771708/
https://www.ncbi.nlm.nih.gov/pubmed/31112626
http://dx.doi.org/10.1002/anie.201903765
Descripción
Sumario:While current M(0)/M(II) based polymerization strategies largely focus on fine‐tuning the catalyst, reagents and conditions for each and every monomer, this report discloses a single method that allows access to a variety of different conjugated polymers within seconds at room temperature. Key to this privileged reactivity is an air‐ and moisture stable dinuclear Pd(I) catalyst. The method is operationally simple, robust and tolerant to air.

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