A General and Air‐tolerant Strategy to Conjugated Polymers within Seconds under Palladium(I) Dimer Catalysis

While current M(0)/M(II) based polymerization strategies largely focus on fine‐tuning the catalyst, reagents and conditions for each and every monomer, this report discloses a single method that allows access to a variety of different conjugated polymers within seconds at room temperature. Key to th...

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Detalles Bibliográficos
Autores principales: Magnin, Guillaume, Clifton, Jamie, Schoenebeck, Franziska
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771708/
https://www.ncbi.nlm.nih.gov/pubmed/31112626
http://dx.doi.org/10.1002/anie.201903765
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author Magnin, Guillaume
Clifton, Jamie
Schoenebeck, Franziska
author_facet Magnin, Guillaume
Clifton, Jamie
Schoenebeck, Franziska
author_sort Magnin, Guillaume
collection PubMed
description While current M(0)/M(II) based polymerization strategies largely focus on fine‐tuning the catalyst, reagents and conditions for each and every monomer, this report discloses a single method that allows access to a variety of different conjugated polymers within seconds at room temperature. Key to this privileged reactivity is an air‐ and moisture stable dinuclear Pd(I) catalyst. The method is operationally simple, robust and tolerant to air.
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spelling pubmed-67717082019-10-07 A General and Air‐tolerant Strategy to Conjugated Polymers within Seconds under Palladium(I) Dimer Catalysis Magnin, Guillaume Clifton, Jamie Schoenebeck, Franziska Angew Chem Int Ed Engl Communications While current M(0)/M(II) based polymerization strategies largely focus on fine‐tuning the catalyst, reagents and conditions for each and every monomer, this report discloses a single method that allows access to a variety of different conjugated polymers within seconds at room temperature. Key to this privileged reactivity is an air‐ and moisture stable dinuclear Pd(I) catalyst. The method is operationally simple, robust and tolerant to air. John Wiley and Sons Inc. 2019-06-13 2019-07-22 /pmc/articles/PMC6771708/ /pubmed/31112626 http://dx.doi.org/10.1002/anie.201903765 Text en © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Communications
Magnin, Guillaume
Clifton, Jamie
Schoenebeck, Franziska
A General and Air‐tolerant Strategy to Conjugated Polymers within Seconds under Palladium(I) Dimer Catalysis
title A General and Air‐tolerant Strategy to Conjugated Polymers within Seconds under Palladium(I) Dimer Catalysis
title_full A General and Air‐tolerant Strategy to Conjugated Polymers within Seconds under Palladium(I) Dimer Catalysis
title_fullStr A General and Air‐tolerant Strategy to Conjugated Polymers within Seconds under Palladium(I) Dimer Catalysis
title_full_unstemmed A General and Air‐tolerant Strategy to Conjugated Polymers within Seconds under Palladium(I) Dimer Catalysis
title_short A General and Air‐tolerant Strategy to Conjugated Polymers within Seconds under Palladium(I) Dimer Catalysis
title_sort general and air‐tolerant strategy to conjugated polymers within seconds under palladium(i) dimer catalysis
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771708/
https://www.ncbi.nlm.nih.gov/pubmed/31112626
http://dx.doi.org/10.1002/anie.201903765
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