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Metallocages for Metal Anions: Highly Charged [Co@Ge(9)](5−) and [Ru@Sn(9)](6−) Clusters Featuring Spherically Encapsulated Co(1−) and Ru(2−) Anions
Endohedral clusters count as molecular models for intermetallic compounds—a class of compounds in which bonding principles are scarcely understood. Herein we report soluble cluster anions with the highest charges on a single cluster to date. The clusters reflect the close analogy between intermetall...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771791/ https://www.ncbi.nlm.nih.gov/pubmed/31298780 http://dx.doi.org/10.1002/anie.201907127 |