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Reactivity of a Sterically Unencumbered α‐Borylated Phosphorus Ylide towards Small Molecules

The influence of substituents on α‐borylated phosphorus ylides (α‐BCPs) has been investigated in a combined experimental and quantum chemical approach. The synthesis and characterization of Me(3)PC(H)B(iBu)(2) (1), consisting of small Me substituents on phosphorous and iBu residues on boron, is repo...

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Detalles Bibliográficos
Autores principales: Radius, Michael, Sattler, Ewald, Berberich, Helga, Breher, Frank
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771871/
https://www.ncbi.nlm.nih.gov/pubmed/31355482
http://dx.doi.org/10.1002/chem.201902681