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Nickel‐Catalyzed Stereodivergent Synthesis of E‐ and Z‐Alkenes by Hydrogenation of Alkynes

A convenient protocol for stereodivergent hydrogenation of alkynes to E‐ and Z‐alkenes by using nickel catalysts was developed. Simple Ni(NO(3))(2)⋅6 H(2)O as a catalyst precursor formed active nanoparticles, which were effective for the semihydrogenation of several alkynes with high selectivity for...

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Detalles Bibliográficos
Autores principales: Murugesan, Kathiravan, Bheeter, Charles Beromeo, Linnebank, Pim R., Spannenberg, Anke, Reek, Joost N. H., Jagadeesh, Rajenahally V., Beller, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6771912/
https://www.ncbi.nlm.nih.gov/pubmed/30977957
http://dx.doi.org/10.1002/cssc.201900784

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