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Hydrogen Bond Directed ortho‐Selective C−H Borylation of Secondary Aromatic Amides
Reported is an iridium catalyst for ortho‐selective C−H borylation of challenging secondary aromatic amide substrates, and the regioselectivity is controlled by hydrogen‐bond interactions. The BAIPy‐Ir catalyst forms three hydrogen bonds with the substrate during the crucial activation step, and all...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6772079/ https://www.ncbi.nlm.nih.gov/pubmed/31237988 http://dx.doi.org/10.1002/anie.201907366 |