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Crystal structure of (15,20-bis(2,3,4,5,6-pentafluorophenyl)-5,10-{(4-methylpyridine-3,5-diyl)bis[(sulfanediylmethylene)[1,1′-biphenyl]-4′,2-diyl]}porphyrinato)nickel(II) dichloromethane x-solvate (x > 1/2)

The title compound, [Ni(C(64)H(33)F(10)N(5)S(2))]·xCH(2)Cl(2), consists of discrete Ni(II) porphyrin complexes, in which the five-coordinate Ni(II) cations are in a distorted square-pyramidal coordination geometry. The four porphyrin nitrogen atoms are located in the basal plane of the pyramid, whe...

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Detalles Bibliográficos
Autores principales:	Gutzeit, Florian, Neumann, Tjorge, Näther, Christian, Herges, Rainer
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2019
Materias:	Research Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6775725/ https://www.ncbi.nlm.nih.gov/pubmed/31636994 http://dx.doi.org/10.1107/S2056989019012453

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6775725/
https://www.ncbi.nlm.nih.gov/pubmed/31636994
http://dx.doi.org/10.1107/S2056989019012453

Crystal structure of (15,20-bis­(2,3,4,5,6-penta­fluoro­phen­yl)-5,10-{(4-methyl­pyridine-3,5-di­yl)bis­[(sulfanediyl­methyl­ene)[1,1′-biphen­yl]-4′,2-di­yl]}porphyrinato)nickel(II) di­chloro­methane x-solvate (x > 1/2)

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Crystal structure of (15,20-bis(2,3,4,5,6-pentafluorophenyl)-5,10-{(4-methylpyridine-3,5-diyl)bis[(sulfanediylmethylene)[1,1′-biphenyl]-4′,2-diyl]}porphyrinato)nickel(II) dichloromethane x-solvate (x > 1/2)