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Crystal structure of (15,20-bis(2,3,4,5,6-pentafluorophenyl)-5,10-{(4-methylpyridine-3,5-diyl)bis[(sulfanediylmethylene)[1,1′-biphenyl]-4′,2-diyl]}porphyrinato)nickel(II) dichloromethane x-solvate (x > 1/2)
The title compound, [Ni(C(64)H(33)F(10)N(5)S(2))]·xCH(2)Cl(2), consists of discrete Ni(II) porphyrin complexes, in which the five-coordinate Ni(II) cations are in a distorted square-pyramidal coordination geometry. The four porphyrin nitrogen atoms are located in the basal plane of the pyramid, whe...
Autores principales: | Gutzeit, Florian, Neumann, Tjorge, Näther, Christian, Herges, Rainer |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6775725/ https://www.ncbi.nlm.nih.gov/pubmed/31636994 http://dx.doi.org/10.1107/S2056989019012453 |
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