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Crystal structure of catena-poly[[[bis(3-oxo-1,3-diphenylprop-1-enolato-κ(2) O,O′)zinc(II)]-μ(2)-tris[4-(pyridin-3-yl)phenyl]amine-κ(2) N:N′] tetrahydrofuran monosolvate]
The reaction of bis(3-oxo-1,3-diphenylprop-1-enolato-κ(2) O,O′)zinc(II), [Zn(dbm)(2)], with tris[4-(pyridin-3-yl)phenyl]amine (T3PyA) in tetrahydrofuran (THF) afforded the title crystalline coordination polymer, {[Zn(C(15)H(11)O(2))(2)(C(33)H(24)N(4))]·C(4)H(8)O}(n). The asymmetric unit conta...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6775726/ https://www.ncbi.nlm.nih.gov/pubmed/31636971 http://dx.doi.org/10.1107/S2056989019012350 |
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author | Kashiwagi, Yukiyasu Kubono, Koji Tamai, Toshiyuki |
author_facet | Kashiwagi, Yukiyasu Kubono, Koji Tamai, Toshiyuki |
author_sort | Kashiwagi, Yukiyasu |
collection | PubMed |
description | The reaction of bis(3-oxo-1,3-diphenylprop-1-enolato-κ(2) O,O′)zinc(II), [Zn(dbm)(2)], with tris[4-(pyridin-3-yl)phenyl]amine (T3PyA) in tetrahydrofuran (THF) afforded the title crystalline coordination polymer, {[Zn(C(15)H(11)O(2))(2)(C(33)H(24)N(4))]·C(4)H(8)O}(n). The asymmetric unit contains two independent halves of Zn(dbm)(2), one T3PyA and one THF. Each Zn(II) atom is located on an inversion centre and adopts an elongated octahedral coordination geometry, ligated by four O atoms of two dbm ligands in equatorial positions and by two N atoms of pyridine moieties from two different bridging T3PyA ligands in axial positions. The crystal packing shows a one-dimensional polymer chain in which the two pyridyl groups of the T3PyA ligand bridge two independent Zn atoms of Zn(dbm)(2). In the crystal, the coordination polymer chains are linked via C—H⋯π interactions into a sheet structure parallel to (010). The sheets are cross-linked via further C—H⋯π interactions into a three-dimensional network. The solvate THF molecule shows disorder over two sets of atomic sites having occupancies of 0.631 (7) and 0.369 (7). |
format | Online Article Text |
id | pubmed-6775726 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-67757262019-10-21 Crystal structure of catena-poly[[[bis(3-oxo-1,3-diphenylprop-1-enolato-κ(2) O,O′)zinc(II)]-μ(2)-tris[4-(pyridin-3-yl)phenyl]amine-κ(2) N:N′] tetrahydrofuran monosolvate] Kashiwagi, Yukiyasu Kubono, Koji Tamai, Toshiyuki Acta Crystallogr E Crystallogr Commun Research Communications The reaction of bis(3-oxo-1,3-diphenylprop-1-enolato-κ(2) O,O′)zinc(II), [Zn(dbm)(2)], with tris[4-(pyridin-3-yl)phenyl]amine (T3PyA) in tetrahydrofuran (THF) afforded the title crystalline coordination polymer, {[Zn(C(15)H(11)O(2))(2)(C(33)H(24)N(4))]·C(4)H(8)O}(n). The asymmetric unit contains two independent halves of Zn(dbm)(2), one T3PyA and one THF. Each Zn(II) atom is located on an inversion centre and adopts an elongated octahedral coordination geometry, ligated by four O atoms of two dbm ligands in equatorial positions and by two N atoms of pyridine moieties from two different bridging T3PyA ligands in axial positions. The crystal packing shows a one-dimensional polymer chain in which the two pyridyl groups of the T3PyA ligand bridge two independent Zn atoms of Zn(dbm)(2). In the crystal, the coordination polymer chains are linked via C—H⋯π interactions into a sheet structure parallel to (010). The sheets are cross-linked via further C—H⋯π interactions into a three-dimensional network. The solvate THF molecule shows disorder over two sets of atomic sites having occupancies of 0.631 (7) and 0.369 (7). International Union of Crystallography 2019-09-10 /pmc/articles/PMC6775726/ /pubmed/31636971 http://dx.doi.org/10.1107/S2056989019012350 Text en © Kashiwagi et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Research Communications Kashiwagi, Yukiyasu Kubono, Koji Tamai, Toshiyuki Crystal structure of catena-poly[[[bis(3-oxo-1,3-diphenylprop-1-enolato-κ(2) O,O′)zinc(II)]-μ(2)-tris[4-(pyridin-3-yl)phenyl]amine-κ(2) N:N′] tetrahydrofuran monosolvate] |
title | Crystal structure of catena-poly[[[bis(3-oxo-1,3-diphenylprop-1-enolato-κ(2)
O,O′)zinc(II)]-μ(2)-tris[4-(pyridin-3-yl)phenyl]amine-κ(2)
N:N′] tetrahydrofuran monosolvate] |
title_full | Crystal structure of catena-poly[[[bis(3-oxo-1,3-diphenylprop-1-enolato-κ(2)
O,O′)zinc(II)]-μ(2)-tris[4-(pyridin-3-yl)phenyl]amine-κ(2)
N:N′] tetrahydrofuran monosolvate] |
title_fullStr | Crystal structure of catena-poly[[[bis(3-oxo-1,3-diphenylprop-1-enolato-κ(2)
O,O′)zinc(II)]-μ(2)-tris[4-(pyridin-3-yl)phenyl]amine-κ(2)
N:N′] tetrahydrofuran monosolvate] |
title_full_unstemmed | Crystal structure of catena-poly[[[bis(3-oxo-1,3-diphenylprop-1-enolato-κ(2)
O,O′)zinc(II)]-μ(2)-tris[4-(pyridin-3-yl)phenyl]amine-κ(2)
N:N′] tetrahydrofuran monosolvate] |
title_short | Crystal structure of catena-poly[[[bis(3-oxo-1,3-diphenylprop-1-enolato-κ(2)
O,O′)zinc(II)]-μ(2)-tris[4-(pyridin-3-yl)phenyl]amine-κ(2)
N:N′] tetrahydrofuran monosolvate] |
title_sort | crystal structure of catena-poly[[[bis(3-oxo-1,3-diphenylprop-1-enolato-κ(2)
o,o′)zinc(ii)]-μ(2)-tris[4-(pyridin-3-yl)phenyl]amine-κ(2)
n:n′] tetrahydrofuran monosolvate] |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6775726/ https://www.ncbi.nlm.nih.gov/pubmed/31636971 http://dx.doi.org/10.1107/S2056989019012350 |
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