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Crystal structure of catena-poly[[[bis­(3-oxo-1,3-di­phenyl­prop-1-enolato-κ(2) O,O′)zinc(II)]-μ(2)-tris­[4-(pyridin-3-yl)phen­yl]amine-κ(2) N:N′] tetra­hydro­furan monosolvate]

The reaction of bis­(3-oxo-1,3-di­phenyl­prop-1-enolato-κ(2) O,O′)zinc(II), [Zn(dbm)(2)], with tris­[4-(pyridin-3-yl)phen­yl]amine (T3PyA) in tetra­hydro­furan (THF) afforded the title crystalline coordination polymer, {[Zn(C(15)H(11)O(2))(2)(C(33)H(24)N(4))]·C(4)H(8)O}(n). The asymmetric unit conta...

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Autores principales: Kashiwagi, Yukiyasu, Kubono, Koji, Tamai, Toshiyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6775726/
https://www.ncbi.nlm.nih.gov/pubmed/31636971
http://dx.doi.org/10.1107/S2056989019012350
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author Kashiwagi, Yukiyasu
Kubono, Koji
Tamai, Toshiyuki
author_facet Kashiwagi, Yukiyasu
Kubono, Koji
Tamai, Toshiyuki
author_sort Kashiwagi, Yukiyasu
collection PubMed
description The reaction of bis­(3-oxo-1,3-di­phenyl­prop-1-enolato-κ(2) O,O′)zinc(II), [Zn(dbm)(2)], with tris­[4-(pyridin-3-yl)phen­yl]amine (T3PyA) in tetra­hydro­furan (THF) afforded the title crystalline coordination polymer, {[Zn(C(15)H(11)O(2))(2)(C(33)H(24)N(4))]·C(4)H(8)O}(n). The asymmetric unit contains two independent halves of Zn(dbm)(2), one T3PyA and one THF. Each Zn(II) atom is located on an inversion centre and adopts an elongated octa­hedral coordination geometry, ligated by four O atoms of two dbm ligands in equatorial positions and by two N atoms of pyridine moieties from two different bridging T3PyA ligands in axial positions. The crystal packing shows a one-dimensional polymer chain in which the two pyridyl groups of the T3PyA ligand bridge two independent Zn atoms of Zn(dbm)(2). In the crystal, the coordination polymer chains are linked via C—H⋯π inter­actions into a sheet structure parallel to (010). The sheets are cross-linked via further C—H⋯π inter­actions into a three-dimensional network. The solvate THF mol­ecule shows disorder over two sets of atomic sites having occupancies of 0.631 (7) and 0.369 (7).
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spelling pubmed-67757262019-10-21 Crystal structure of catena-poly[[[bis­(3-oxo-1,3-di­phenyl­prop-1-enolato-κ(2) O,O′)zinc(II)]-μ(2)-tris­[4-(pyridin-3-yl)phen­yl]amine-κ(2) N:N′] tetra­hydro­furan monosolvate] Kashiwagi, Yukiyasu Kubono, Koji Tamai, Toshiyuki Acta Crystallogr E Crystallogr Commun Research Communications The reaction of bis­(3-oxo-1,3-di­phenyl­prop-1-enolato-κ(2) O,O′)zinc(II), [Zn(dbm)(2)], with tris­[4-(pyridin-3-yl)phen­yl]amine (T3PyA) in tetra­hydro­furan (THF) afforded the title crystalline coordination polymer, {[Zn(C(15)H(11)O(2))(2)(C(33)H(24)N(4))]·C(4)H(8)O}(n). The asymmetric unit contains two independent halves of Zn(dbm)(2), one T3PyA and one THF. Each Zn(II) atom is located on an inversion centre and adopts an elongated octa­hedral coordination geometry, ligated by four O atoms of two dbm ligands in equatorial positions and by two N atoms of pyridine moieties from two different bridging T3PyA ligands in axial positions. The crystal packing shows a one-dimensional polymer chain in which the two pyridyl groups of the T3PyA ligand bridge two independent Zn atoms of Zn(dbm)(2). In the crystal, the coordination polymer chains are linked via C—H⋯π inter­actions into a sheet structure parallel to (010). The sheets are cross-linked via further C—H⋯π inter­actions into a three-dimensional network. The solvate THF mol­ecule shows disorder over two sets of atomic sites having occupancies of 0.631 (7) and 0.369 (7). International Union of Crystallography 2019-09-10 /pmc/articles/PMC6775726/ /pubmed/31636971 http://dx.doi.org/10.1107/S2056989019012350 Text en © Kashiwagi et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Kashiwagi, Yukiyasu
Kubono, Koji
Tamai, Toshiyuki
Crystal structure of catena-poly[[[bis­(3-oxo-1,3-di­phenyl­prop-1-enolato-κ(2) O,O′)zinc(II)]-μ(2)-tris­[4-(pyridin-3-yl)phen­yl]amine-κ(2) N:N′] tetra­hydro­furan monosolvate]
title Crystal structure of catena-poly[[[bis­(3-oxo-1,3-di­phenyl­prop-1-enolato-κ(2) O,O′)zinc(II)]-μ(2)-tris­[4-(pyridin-3-yl)phen­yl]amine-κ(2) N:N′] tetra­hydro­furan monosolvate]
title_full Crystal structure of catena-poly[[[bis­(3-oxo-1,3-di­phenyl­prop-1-enolato-κ(2) O,O′)zinc(II)]-μ(2)-tris­[4-(pyridin-3-yl)phen­yl]amine-κ(2) N:N′] tetra­hydro­furan monosolvate]
title_fullStr Crystal structure of catena-poly[[[bis­(3-oxo-1,3-di­phenyl­prop-1-enolato-κ(2) O,O′)zinc(II)]-μ(2)-tris­[4-(pyridin-3-yl)phen­yl]amine-κ(2) N:N′] tetra­hydro­furan monosolvate]
title_full_unstemmed Crystal structure of catena-poly[[[bis­(3-oxo-1,3-di­phenyl­prop-1-enolato-κ(2) O,O′)zinc(II)]-μ(2)-tris­[4-(pyridin-3-yl)phen­yl]amine-κ(2) N:N′] tetra­hydro­furan monosolvate]
title_short Crystal structure of catena-poly[[[bis­(3-oxo-1,3-di­phenyl­prop-1-enolato-κ(2) O,O′)zinc(II)]-μ(2)-tris­[4-(pyridin-3-yl)phen­yl]amine-κ(2) N:N′] tetra­hydro­furan monosolvate]
title_sort crystal structure of catena-poly[[[bis­(3-oxo-1,3-di­phenyl­prop-1-enolato-κ(2) o,o′)zinc(ii)]-μ(2)-tris­[4-(pyridin-3-yl)phen­yl]amine-κ(2) n:n′] tetra­hydro­furan monosolvate]
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6775726/
https://www.ncbi.nlm.nih.gov/pubmed/31636971
http://dx.doi.org/10.1107/S2056989019012350
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