Crystal structure of tetra­kis­(tetra­hydro­furan-κO)bis­(tri­fluoro­methane­sulfonato-κO)iron(II)

The title compound, [Fe(CF(3)SO(3))(2)(C(4)H(8)O)(4)], is octa­hedral with two tri­fluoro­methane­sulfonate ligands in trans positions and four tetra­hydro­furane mol­ecules in the equatorial plane. By the conformation of the ligands the complex is chiral in the crystal packing. The compound crystal...

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Detalles Bibliográficos
Autores principales: Riemersma, Charl F., Monkcom, Emily C., Klein Gebbink, Robertus J. M., Lutz, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6775732/
https://www.ncbi.nlm.nih.gov/pubmed/31636992
http://dx.doi.org/10.1107/S2056989019013094
Descripción
Sumario:The title compound, [Fe(CF(3)SO(3))(2)(C(4)H(8)O)(4)], is octa­hedral with two tri­fluoro­methane­sulfonate ligands in trans positions and four tetra­hydro­furane mol­ecules in the equatorial plane. By the conformation of the ligands the complex is chiral in the crystal packing. The compound crystallizes in the Sohncke space group P2(1)2(1)2(1) and is enanti­omerically pure. The packing of the mol­ecules is determined by weak C—H⋯O hydrogen bonds. The crystal studied was refined as a two-component inversion twin.

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