(N,N-Diiso­propyl­dithio­carbamato)tri­phenyl­tin(IV): crystal structure, Hirshfeld surface analysis and computational study

The crystal and mol­ecular structures of the title triorganotin di­thio­carbamate, [Sn(C(6)H(5))(3)(C(7)H(14)NS(2))], are described. The mol­ecular geometry about the metal atom is highly distorted being based on a C(3)S tetra­hedron as the di­thio­carbamate ligand is asymmetrically chelating to the tin centre. The close approach of the second thione-S atom [Sn⋯S = 2.9264 (4) Å] is largely responsible for the distortion. The mol­ecular packing is almost devoid of directional inter­actions with only weak phenyl-C—H⋯C(phen­yl) inter­actions, leading to centrosymmetric dimeric aggregates, being noted. An analysis of the calculated Hirshfeld surface points to the significance of H⋯H contacts, which contribute 66.6% of all contacts to the surface, with C⋯H/H⋯C [26.8%] and S⋯H/H⋯H [6.6%] contacts making up the balance.