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Crystal structure of bis­[2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]bis­(nitrato-κO)cadmium(II)

In the title compound, [Cd(NO(3))(2)(C(13)H(11)N(3))(2)], the Cd(II) atom lies on a twofold rotation axis and is coordinated by four N atoms and two O atoms, provided by two bidentate 2-(1H-benzimidazol-2-yl)aniline ligands, and two nitrato O atoms, forming a distorted octa­hedral geometry [range of...

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Autores principales: Kim, Yongtae, Kang, Sung Kwon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6775742/
https://www.ncbi.nlm.nih.gov/pubmed/31636976
http://dx.doi.org/10.1107/S2056989019012416
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author Kim, Yongtae
Kang, Sung Kwon
author_facet Kim, Yongtae
Kang, Sung Kwon
author_sort Kim, Yongtae
collection PubMed
description In the title compound, [Cd(NO(3))(2)(C(13)H(11)N(3))(2)], the Cd(II) atom lies on a twofold rotation axis and is coordinated by four N atoms and two O atoms, provided by two bidentate 2-(1H-benzimidazol-2-yl)aniline ligands, and two nitrato O atoms, forming a distorted octa­hedral geometry [range of bond angles around the Cd atom = 73.82 (2)–106.95 (8)°]. In the ligand, the dihedral angle between the aniline ring and the benzimidazole ring system is 30.43 (7)°. The discrete complex mol­ecule is stabilized by an intra­molecular N—H⋯O hydrogen bond. In the crystal, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules, forming a three-dimensional network.
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spelling pubmed-67757422019-10-21 Crystal structure of bis­[2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]bis­(nitrato-κO)cadmium(II) Kim, Yongtae Kang, Sung Kwon Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [Cd(NO(3))(2)(C(13)H(11)N(3))(2)], the Cd(II) atom lies on a twofold rotation axis and is coordinated by four N atoms and two O atoms, provided by two bidentate 2-(1H-benzimidazol-2-yl)aniline ligands, and two nitrato O atoms, forming a distorted octa­hedral geometry [range of bond angles around the Cd atom = 73.82 (2)–106.95 (8)°]. In the ligand, the dihedral angle between the aniline ring and the benzimidazole ring system is 30.43 (7)°. The discrete complex mol­ecule is stabilized by an intra­molecular N—H⋯O hydrogen bond. In the crystal, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules, forming a three-dimensional network. International Union of Crystallography 2019-09-12 /pmc/articles/PMC6775742/ /pubmed/31636976 http://dx.doi.org/10.1107/S2056989019012416 Text en © Kim and Kang 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Kim, Yongtae
Kang, Sung Kwon
Crystal structure of bis­[2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]bis­(nitrato-κO)cadmium(II)
title Crystal structure of bis­[2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]bis­(nitrato-κO)cadmium(II)
title_full Crystal structure of bis­[2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]bis­(nitrato-κO)cadmium(II)
title_fullStr Crystal structure of bis­[2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]bis­(nitrato-κO)cadmium(II)
title_full_unstemmed Crystal structure of bis­[2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]bis­(nitrato-κO)cadmium(II)
title_short Crystal structure of bis­[2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]bis­(nitrato-κO)cadmium(II)
title_sort crystal structure of bis­[2-(1h-benzimidazol-2-yl-κn (3))aniline-κn]bis­(nitrato-κo)cadmium(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6775742/
https://www.ncbi.nlm.nih.gov/pubmed/31636976
http://dx.doi.org/10.1107/S2056989019012416
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