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Crystal structure of bis[2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]bis(nitrato-κO)cadmium(II)
In the title compound, [Cd(NO(3))(2)(C(13)H(11)N(3))(2)], the Cd(II) atom lies on a twofold rotation axis and is coordinated by four N atoms and two O atoms, provided by two bidentate 2-(1H-benzimidazol-2-yl)aniline ligands, and two nitrato O atoms, forming a distorted octahedral geometry [range of...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6775742/ https://www.ncbi.nlm.nih.gov/pubmed/31636976 http://dx.doi.org/10.1107/S2056989019012416 |
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author | Kim, Yongtae Kang, Sung Kwon |
author_facet | Kim, Yongtae Kang, Sung Kwon |
author_sort | Kim, Yongtae |
collection | PubMed |
description | In the title compound, [Cd(NO(3))(2)(C(13)H(11)N(3))(2)], the Cd(II) atom lies on a twofold rotation axis and is coordinated by four N atoms and two O atoms, provided by two bidentate 2-(1H-benzimidazol-2-yl)aniline ligands, and two nitrato O atoms, forming a distorted octahedral geometry [range of bond angles around the Cd atom = 73.82 (2)–106.95 (8)°]. In the ligand, the dihedral angle between the aniline ring and the benzimidazole ring system is 30.43 (7)°. The discrete complex molecule is stabilized by an intramolecular N—H⋯O hydrogen bond. In the crystal, intermolecular N—H⋯O hydrogen bonds link the molecules, forming a three-dimensional network. |
format | Online Article Text |
id | pubmed-6775742 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-67757422019-10-21 Crystal structure of bis[2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]bis(nitrato-κO)cadmium(II) Kim, Yongtae Kang, Sung Kwon Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [Cd(NO(3))(2)(C(13)H(11)N(3))(2)], the Cd(II) atom lies on a twofold rotation axis and is coordinated by four N atoms and two O atoms, provided by two bidentate 2-(1H-benzimidazol-2-yl)aniline ligands, and two nitrato O atoms, forming a distorted octahedral geometry [range of bond angles around the Cd atom = 73.82 (2)–106.95 (8)°]. In the ligand, the dihedral angle between the aniline ring and the benzimidazole ring system is 30.43 (7)°. The discrete complex molecule is stabilized by an intramolecular N—H⋯O hydrogen bond. In the crystal, intermolecular N—H⋯O hydrogen bonds link the molecules, forming a three-dimensional network. International Union of Crystallography 2019-09-12 /pmc/articles/PMC6775742/ /pubmed/31636976 http://dx.doi.org/10.1107/S2056989019012416 Text en © Kim and Kang 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Research Communications Kim, Yongtae Kang, Sung Kwon Crystal structure of bis[2-(1H-benzimidazol-2-yl-κN (3))aniline-κN]bis(nitrato-κO)cadmium(II) |
title | Crystal structure of bis[2-(1H-benzimidazol-2-yl-κN
(3))aniline-κN]bis(nitrato-κO)cadmium(II) |
title_full | Crystal structure of bis[2-(1H-benzimidazol-2-yl-κN
(3))aniline-κN]bis(nitrato-κO)cadmium(II) |
title_fullStr | Crystal structure of bis[2-(1H-benzimidazol-2-yl-κN
(3))aniline-κN]bis(nitrato-κO)cadmium(II) |
title_full_unstemmed | Crystal structure of bis[2-(1H-benzimidazol-2-yl-κN
(3))aniline-κN]bis(nitrato-κO)cadmium(II) |
title_short | Crystal structure of bis[2-(1H-benzimidazol-2-yl-κN
(3))aniline-κN]bis(nitrato-κO)cadmium(II) |
title_sort | crystal structure of bis[2-(1h-benzimidazol-2-yl-κn
(3))aniline-κn]bis(nitrato-κo)cadmium(ii) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6775742/ https://www.ncbi.nlm.nih.gov/pubmed/31636976 http://dx.doi.org/10.1107/S2056989019012416 |
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