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The crystal structure of ((cyclo­hexyl­amino){(Z)-2-[(E)-5-meth­oxy-3-nitro-2-oxido­benzyl­idene-κO]hydrazin-1-yl­idene-κN (2)}methane­thiol­ato-κS)(dimethyl sulfoxide-κS)platinum(II): a supra­molecular two-dimensional network

The Pt(II) atom in the title complex, [Pt(C(15)H(18)N(4)O(4)S)(C(2)H(6)OS)], exists within a square-planar NS(2)O donor set provided by the N, S, O atoms of the di-anionic tridentate thio­semicarbazo ligand and a dimethyl sulfoxide S atom. The two chelate rings are coplanar, subtending a dihedral an...

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Autores principales: Arafath, Md. Azharul, Kwong, Huey Chong, Adam, Farook
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6775752/
https://www.ncbi.nlm.nih.gov/pubmed/31636980
http://dx.doi.org/10.1107/S2056989019012623
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author Arafath, Md. Azharul
Kwong, Huey Chong
Adam, Farook
author_facet Arafath, Md. Azharul
Kwong, Huey Chong
Adam, Farook
author_sort Arafath, Md. Azharul
collection PubMed
description The Pt(II) atom in the title complex, [Pt(C(15)H(18)N(4)O(4)S)(C(2)H(6)OS)], exists within a square-planar NS(2)O donor set provided by the N, S, O atoms of the di-anionic tridentate thio­semicarbazo ligand and a dimethyl sulfoxide S atom. The two chelate rings are coplanar, subtending a dihedral angle of 1.51 (7)°. The maximum deviation from an ideal square-planar geometry is seen in the five-membered chelate ring with an S—Pt—S bite angle of 96.45 (2)°. In the crystal, mol­ecules are linked via N—H⋯O, C—H⋯O, C—H⋯N and C—H⋯π inter­actions into two-dimensional networks lying parallel to the ab plane. The conformations of related cyclo­hexyl­hydrazine-1-carbo­thio­amide ligands are compared to that of the title compound.
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spelling pubmed-67757522019-10-21 The crystal structure of ((cyclo­hexyl­amino){(Z)-2-[(E)-5-meth­oxy-3-nitro-2-oxido­benzyl­idene-κO]hydrazin-1-yl­idene-κN (2)}methane­thiol­ato-κS)(dimethyl sulfoxide-κS)platinum(II): a supra­molecular two-dimensional network Arafath, Md. Azharul Kwong, Huey Chong Adam, Farook Acta Crystallogr E Crystallogr Commun Research Communications The Pt(II) atom in the title complex, [Pt(C(15)H(18)N(4)O(4)S)(C(2)H(6)OS)], exists within a square-planar NS(2)O donor set provided by the N, S, O atoms of the di-anionic tridentate thio­semicarbazo ligand and a dimethyl sulfoxide S atom. The two chelate rings are coplanar, subtending a dihedral angle of 1.51 (7)°. The maximum deviation from an ideal square-planar geometry is seen in the five-membered chelate ring with an S—Pt—S bite angle of 96.45 (2)°. In the crystal, mol­ecules are linked via N—H⋯O, C—H⋯O, C—H⋯N and C—H⋯π inter­actions into two-dimensional networks lying parallel to the ab plane. The conformations of related cyclo­hexyl­hydrazine-1-carbo­thio­amide ligands are compared to that of the title compound. International Union of Crystallography 2019-09-12 /pmc/articles/PMC6775752/ /pubmed/31636980 http://dx.doi.org/10.1107/S2056989019012623 Text en © Arafath et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Arafath, Md. Azharul
Kwong, Huey Chong
Adam, Farook
The crystal structure of ((cyclo­hexyl­amino){(Z)-2-[(E)-5-meth­oxy-3-nitro-2-oxido­benzyl­idene-κO]hydrazin-1-yl­idene-κN (2)}methane­thiol­ato-κS)(dimethyl sulfoxide-κS)platinum(II): a supra­molecular two-dimensional network
title The crystal structure of ((cyclo­hexyl­amino){(Z)-2-[(E)-5-meth­oxy-3-nitro-2-oxido­benzyl­idene-κO]hydrazin-1-yl­idene-κN (2)}methane­thiol­ato-κS)(dimethyl sulfoxide-κS)platinum(II): a supra­molecular two-dimensional network
title_full The crystal structure of ((cyclo­hexyl­amino){(Z)-2-[(E)-5-meth­oxy-3-nitro-2-oxido­benzyl­idene-κO]hydrazin-1-yl­idene-κN (2)}methane­thiol­ato-κS)(dimethyl sulfoxide-κS)platinum(II): a supra­molecular two-dimensional network
title_fullStr The crystal structure of ((cyclo­hexyl­amino){(Z)-2-[(E)-5-meth­oxy-3-nitro-2-oxido­benzyl­idene-κO]hydrazin-1-yl­idene-κN (2)}methane­thiol­ato-κS)(dimethyl sulfoxide-κS)platinum(II): a supra­molecular two-dimensional network
title_full_unstemmed The crystal structure of ((cyclo­hexyl­amino){(Z)-2-[(E)-5-meth­oxy-3-nitro-2-oxido­benzyl­idene-κO]hydrazin-1-yl­idene-κN (2)}methane­thiol­ato-κS)(dimethyl sulfoxide-κS)platinum(II): a supra­molecular two-dimensional network
title_short The crystal structure of ((cyclo­hexyl­amino){(Z)-2-[(E)-5-meth­oxy-3-nitro-2-oxido­benzyl­idene-κO]hydrazin-1-yl­idene-κN (2)}methane­thiol­ato-κS)(dimethyl sulfoxide-κS)platinum(II): a supra­molecular two-dimensional network
title_sort crystal structure of ((cyclo­hexyl­amino){(z)-2-[(e)-5-meth­oxy-3-nitro-2-oxido­benzyl­idene-κo]hydrazin-1-yl­idene-κn (2)}methane­thiol­ato-κs)(dimethyl sulfoxide-κs)platinum(ii): a supra­molecular two-dimensional network
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6775752/
https://www.ncbi.nlm.nih.gov/pubmed/31636980
http://dx.doi.org/10.1107/S2056989019012623
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