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The crystal structure of ((cyclohexylamino){(Z)-2-[(E)-5-methoxy-3-nitro-2-oxidobenzylidene-κO]hydrazin-1-ylidene-κN (2)}methanethiolato-κS)(dimethyl sulfoxide-κS)platinum(II): a supramolecular two-dimensional network
The Pt(II) atom in the title complex, [Pt(C(15)H(18)N(4)O(4)S)(C(2)H(6)OS)], exists within a square-planar NS(2)O donor set provided by the N, S, O atoms of the di-anionic tridentate thiosemicarbazo ligand and a dimethyl sulfoxide S atom. The two chelate rings are coplanar, subtending a dihedral an...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6775752/ https://www.ncbi.nlm.nih.gov/pubmed/31636980 http://dx.doi.org/10.1107/S2056989019012623 |
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author | Arafath, Md. Azharul Kwong, Huey Chong Adam, Farook |
author_facet | Arafath, Md. Azharul Kwong, Huey Chong Adam, Farook |
author_sort | Arafath, Md. Azharul |
collection | PubMed |
description | The Pt(II) atom in the title complex, [Pt(C(15)H(18)N(4)O(4)S)(C(2)H(6)OS)], exists within a square-planar NS(2)O donor set provided by the N, S, O atoms of the di-anionic tridentate thiosemicarbazo ligand and a dimethyl sulfoxide S atom. The two chelate rings are coplanar, subtending a dihedral angle of 1.51 (7)°. The maximum deviation from an ideal square-planar geometry is seen in the five-membered chelate ring with an S—Pt—S bite angle of 96.45 (2)°. In the crystal, molecules are linked via N—H⋯O, C—H⋯O, C—H⋯N and C—H⋯π interactions into two-dimensional networks lying parallel to the ab plane. The conformations of related cyclohexylhydrazine-1-carbothioamide ligands are compared to that of the title compound. |
format | Online Article Text |
id | pubmed-6775752 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-67757522019-10-21 The crystal structure of ((cyclohexylamino){(Z)-2-[(E)-5-methoxy-3-nitro-2-oxidobenzylidene-κO]hydrazin-1-ylidene-κN (2)}methanethiolato-κS)(dimethyl sulfoxide-κS)platinum(II): a supramolecular two-dimensional network Arafath, Md. Azharul Kwong, Huey Chong Adam, Farook Acta Crystallogr E Crystallogr Commun Research Communications The Pt(II) atom in the title complex, [Pt(C(15)H(18)N(4)O(4)S)(C(2)H(6)OS)], exists within a square-planar NS(2)O donor set provided by the N, S, O atoms of the di-anionic tridentate thiosemicarbazo ligand and a dimethyl sulfoxide S atom. The two chelate rings are coplanar, subtending a dihedral angle of 1.51 (7)°. The maximum deviation from an ideal square-planar geometry is seen in the five-membered chelate ring with an S—Pt—S bite angle of 96.45 (2)°. In the crystal, molecules are linked via N—H⋯O, C—H⋯O, C—H⋯N and C—H⋯π interactions into two-dimensional networks lying parallel to the ab plane. The conformations of related cyclohexylhydrazine-1-carbothioamide ligands are compared to that of the title compound. International Union of Crystallography 2019-09-12 /pmc/articles/PMC6775752/ /pubmed/31636980 http://dx.doi.org/10.1107/S2056989019012623 Text en © Arafath et al. 2019 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Research Communications Arafath, Md. Azharul Kwong, Huey Chong Adam, Farook The crystal structure of ((cyclohexylamino){(Z)-2-[(E)-5-methoxy-3-nitro-2-oxidobenzylidene-κO]hydrazin-1-ylidene-κN (2)}methanethiolato-κS)(dimethyl sulfoxide-κS)platinum(II): a supramolecular two-dimensional network |
title | The crystal structure of ((cyclohexylamino){(Z)-2-[(E)-5-methoxy-3-nitro-2-oxidobenzylidene-κO]hydrazin-1-ylidene-κN
(2)}methanethiolato-κS)(dimethyl sulfoxide-κS)platinum(II): a supramolecular two-dimensional network |
title_full | The crystal structure of ((cyclohexylamino){(Z)-2-[(E)-5-methoxy-3-nitro-2-oxidobenzylidene-κO]hydrazin-1-ylidene-κN
(2)}methanethiolato-κS)(dimethyl sulfoxide-κS)platinum(II): a supramolecular two-dimensional network |
title_fullStr | The crystal structure of ((cyclohexylamino){(Z)-2-[(E)-5-methoxy-3-nitro-2-oxidobenzylidene-κO]hydrazin-1-ylidene-κN
(2)}methanethiolato-κS)(dimethyl sulfoxide-κS)platinum(II): a supramolecular two-dimensional network |
title_full_unstemmed | The crystal structure of ((cyclohexylamino){(Z)-2-[(E)-5-methoxy-3-nitro-2-oxidobenzylidene-κO]hydrazin-1-ylidene-κN
(2)}methanethiolato-κS)(dimethyl sulfoxide-κS)platinum(II): a supramolecular two-dimensional network |
title_short | The crystal structure of ((cyclohexylamino){(Z)-2-[(E)-5-methoxy-3-nitro-2-oxidobenzylidene-κO]hydrazin-1-ylidene-κN
(2)}methanethiolato-κS)(dimethyl sulfoxide-κS)platinum(II): a supramolecular two-dimensional network |
title_sort | crystal structure of ((cyclohexylamino){(z)-2-[(e)-5-methoxy-3-nitro-2-oxidobenzylidene-κo]hydrazin-1-ylidene-κn
(2)}methanethiolato-κs)(dimethyl sulfoxide-κs)platinum(ii): a supramolecular two-dimensional network |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6775752/ https://www.ncbi.nlm.nih.gov/pubmed/31636980 http://dx.doi.org/10.1107/S2056989019012623 |
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