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Waste Toner-Derived Carbon/Fe(3)O(4) Nanocomposite for High-Performance Supercapacitor

[Image: see text] Electronic waste management is one of the key challenges for the green revolution without affecting the environment. The wide use of printer devices has brought a horde of discarded waste toner, which release ∼6000 tons of processed carbon powder into the atmosphere every year that...

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Autores principales: Kaipannan, Subramani, Govindarajan, Kaviarasan, Sundaramoorthy, Santhoshkumar, Marappan, Sathish
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6776962/
https://www.ncbi.nlm.nih.gov/pubmed/31592452
http://dx.doi.org/10.1021/acsomega.9b01337
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author Kaipannan, Subramani
Govindarajan, Kaviarasan
Sundaramoorthy, Santhoshkumar
Marappan, Sathish
author_facet Kaipannan, Subramani
Govindarajan, Kaviarasan
Sundaramoorthy, Santhoshkumar
Marappan, Sathish
author_sort Kaipannan, Subramani
collection PubMed
description [Image: see text] Electronic waste management is one of the key challenges for the green revolution without affecting the environment. The wide use of printer devices has brought a horde of discarded waste toner, which release ∼6000 tons of processed carbon powder into the atmosphere every year that would essentially pollute the atmosphere. Here, we propose a one-step thermal conversion of waste toner powder into carbon/Fe(3)O(4) nanocomposites for energy storage applications. Recovered toner carbon (RTC) and toner carbon calcined at 300 °C (RTC-300) were characterized using various analytical tools. From the FE-SEM analysis, the presence of carbon particles with uniformly decorated Fe(3)O(4) nanoparticles was confirmed. RTC-300 carbon was used as an electrode material for supercapacitors, and it exhibited a high specific capacitance of 536 F/g at a current density of 3 A/g, which is almost six times higher than that of the commercial mesoporous graphitized carbon black. RTC-300 showed excellent electrochemical stability of 97% over 5000 cycles at a high current density of 20 A/g. The fabricated symmetric cell using RTC-300 electrode materials in an aqueous electrolyte with a cell voltage of 1.8 V delivered a high energy and high-power density of 42 W h/kg and 14.5 kW/kg, respectively. The fabricated device is stable up to 20,000 cycles at a high current density of 20 A/g with a loss of 23% capacitance.
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spelling pubmed-67769622019-10-07 Waste Toner-Derived Carbon/Fe(3)O(4) Nanocomposite for High-Performance Supercapacitor Kaipannan, Subramani Govindarajan, Kaviarasan Sundaramoorthy, Santhoshkumar Marappan, Sathish ACS Omega [Image: see text] Electronic waste management is one of the key challenges for the green revolution without affecting the environment. The wide use of printer devices has brought a horde of discarded waste toner, which release ∼6000 tons of processed carbon powder into the atmosphere every year that would essentially pollute the atmosphere. Here, we propose a one-step thermal conversion of waste toner powder into carbon/Fe(3)O(4) nanocomposites for energy storage applications. Recovered toner carbon (RTC) and toner carbon calcined at 300 °C (RTC-300) were characterized using various analytical tools. From the FE-SEM analysis, the presence of carbon particles with uniformly decorated Fe(3)O(4) nanoparticles was confirmed. RTC-300 carbon was used as an electrode material for supercapacitors, and it exhibited a high specific capacitance of 536 F/g at a current density of 3 A/g, which is almost six times higher than that of the commercial mesoporous graphitized carbon black. RTC-300 showed excellent electrochemical stability of 97% over 5000 cycles at a high current density of 20 A/g. The fabricated symmetric cell using RTC-300 electrode materials in an aqueous electrolyte with a cell voltage of 1.8 V delivered a high energy and high-power density of 42 W h/kg and 14.5 kW/kg, respectively. The fabricated device is stable up to 20,000 cycles at a high current density of 20 A/g with a loss of 23% capacitance. American Chemical Society 2019-09-16 /pmc/articles/PMC6776962/ /pubmed/31592452 http://dx.doi.org/10.1021/acsomega.9b01337 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Kaipannan, Subramani
Govindarajan, Kaviarasan
Sundaramoorthy, Santhoshkumar
Marappan, Sathish
Waste Toner-Derived Carbon/Fe(3)O(4) Nanocomposite for High-Performance Supercapacitor
title Waste Toner-Derived Carbon/Fe(3)O(4) Nanocomposite for High-Performance Supercapacitor
title_full Waste Toner-Derived Carbon/Fe(3)O(4) Nanocomposite for High-Performance Supercapacitor
title_fullStr Waste Toner-Derived Carbon/Fe(3)O(4) Nanocomposite for High-Performance Supercapacitor
title_full_unstemmed Waste Toner-Derived Carbon/Fe(3)O(4) Nanocomposite for High-Performance Supercapacitor
title_short Waste Toner-Derived Carbon/Fe(3)O(4) Nanocomposite for High-Performance Supercapacitor
title_sort waste toner-derived carbon/fe(3)o(4) nanocomposite for high-performance supercapacitor
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6776962/
https://www.ncbi.nlm.nih.gov/pubmed/31592452
http://dx.doi.org/10.1021/acsomega.9b01337
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