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High Specific Capacitance Electrode Material for Supercapacitors Based on Resin-Derived Nitrogen-Doped Porous Carbons

[Image: see text] Carbon-based materials, as electrodes for supercapacitors, have attracted tremendous attention. Therefore, nitrogen-doped porous carbons (NPCs) were prepared through a facile carbonization/activation strategy by treating different mass ratios of melamine–urea–formaldehyde resin and...

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Autores principales: Yu, Jing, Fu, Ning, Zhao, Jing, Liu, Rui, Li, Feng, Du, Yuchuan, Yang, Zhenglong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6776963/
https://www.ncbi.nlm.nih.gov/pubmed/31592460
http://dx.doi.org/10.1021/acsomega.9b01916
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author Yu, Jing
Fu, Ning
Zhao, Jing
Liu, Rui
Li, Feng
Du, Yuchuan
Yang, Zhenglong
author_facet Yu, Jing
Fu, Ning
Zhao, Jing
Liu, Rui
Li, Feng
Du, Yuchuan
Yang, Zhenglong
author_sort Yu, Jing
collection PubMed
description [Image: see text] Carbon-based materials, as electrodes for supercapacitors, have attracted tremendous attention. Therefore, nitrogen-doped porous carbons (NPCs) were prepared through a facile carbonization/activation strategy by treating different mass ratios of melamine–urea–formaldehyde resin and KOH. It is clearly demonstrated that because of the introduction of KOH, the resulting NPCs were shown to have increased specific surface area and a rich pore structure, and the best sample possessed a large specific surface area of 2248 m(2) g(–1) and high N content, which contributed to the good electrochemical performance for supercapacitors. Accordingly, a three-electrode system assembles NPCs as an electrode using aqueous KOH solution; the specific capacitance was 341 F g(–1) under the current density of 1 A g(–1) and retained a specific capacitance of almost 92% after 5000 cycles. The maximum energy output for a symmetrical solid-state supercapacitor with NPCs as the electrode material was 9.60 W h kg(–1) at 1 A g(–1). NPCs have promising applications on high-performance supercapacitors and other energy-storage devices.
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spelling pubmed-67769632019-10-07 High Specific Capacitance Electrode Material for Supercapacitors Based on Resin-Derived Nitrogen-Doped Porous Carbons Yu, Jing Fu, Ning Zhao, Jing Liu, Rui Li, Feng Du, Yuchuan Yang, Zhenglong ACS Omega [Image: see text] Carbon-based materials, as electrodes for supercapacitors, have attracted tremendous attention. Therefore, nitrogen-doped porous carbons (NPCs) were prepared through a facile carbonization/activation strategy by treating different mass ratios of melamine–urea–formaldehyde resin and KOH. It is clearly demonstrated that because of the introduction of KOH, the resulting NPCs were shown to have increased specific surface area and a rich pore structure, and the best sample possessed a large specific surface area of 2248 m(2) g(–1) and high N content, which contributed to the good electrochemical performance for supercapacitors. Accordingly, a three-electrode system assembles NPCs as an electrode using aqueous KOH solution; the specific capacitance was 341 F g(–1) under the current density of 1 A g(–1) and retained a specific capacitance of almost 92% after 5000 cycles. The maximum energy output for a symmetrical solid-state supercapacitor with NPCs as the electrode material was 9.60 W h kg(–1) at 1 A g(–1). NPCs have promising applications on high-performance supercapacitors and other energy-storage devices. American Chemical Society 2019-09-19 /pmc/articles/PMC6776963/ /pubmed/31592460 http://dx.doi.org/10.1021/acsomega.9b01916 Text en Copyright © 2019 American Chemical Society This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License (http://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html) , which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes.
spellingShingle Yu, Jing
Fu, Ning
Zhao, Jing
Liu, Rui
Li, Feng
Du, Yuchuan
Yang, Zhenglong
High Specific Capacitance Electrode Material for Supercapacitors Based on Resin-Derived Nitrogen-Doped Porous Carbons
title High Specific Capacitance Electrode Material for Supercapacitors Based on Resin-Derived Nitrogen-Doped Porous Carbons
title_full High Specific Capacitance Electrode Material for Supercapacitors Based on Resin-Derived Nitrogen-Doped Porous Carbons
title_fullStr High Specific Capacitance Electrode Material for Supercapacitors Based on Resin-Derived Nitrogen-Doped Porous Carbons
title_full_unstemmed High Specific Capacitance Electrode Material for Supercapacitors Based on Resin-Derived Nitrogen-Doped Porous Carbons
title_short High Specific Capacitance Electrode Material for Supercapacitors Based on Resin-Derived Nitrogen-Doped Porous Carbons
title_sort high specific capacitance electrode material for supercapacitors based on resin-derived nitrogen-doped porous carbons
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6776963/
https://www.ncbi.nlm.nih.gov/pubmed/31592460
http://dx.doi.org/10.1021/acsomega.9b01916
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