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Catalytic Deoxygenation of the Oil and Biodiesel of Licuri (Syagrus coronata) To Obtain n-Alkanes with Chains in the Range of Biojet Fuels

[Image: see text] Aviation industry has the challenge of halving CO(2) emissions by 2050, as compared to 2005. An alternative are drop-in biofuels, which are sustainable and fully compatible with aircraft engines and also can be mixed with fossil jet fuel. Among the feedstock for biojet fuel product...

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Autores principales: Araújo, Pedro H. M., Maia, Ary S., Cordeiro, Angela M. T. M., Gondim, Amanda D., Santos, Nataly A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6776966/
https://www.ncbi.nlm.nih.gov/pubmed/31592170
http://dx.doi.org/10.1021/acsomega.9b01737
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author Araújo, Pedro H. M.
Maia, Ary S.
Cordeiro, Angela M. T. M.
Gondim, Amanda D.
Santos, Nataly A.
author_facet Araújo, Pedro H. M.
Maia, Ary S.
Cordeiro, Angela M. T. M.
Gondim, Amanda D.
Santos, Nataly A.
author_sort Araújo, Pedro H. M.
collection PubMed
description [Image: see text] Aviation industry has the challenge of halving CO(2) emissions by 2050, as compared to 2005. An alternative are drop-in biofuels, which are sustainable and fully compatible with aircraft engines and also can be mixed with fossil jet fuel. Among the feedstock for biojet fuel production, licuri (Syagrus coronata) can be highlighted as most of its fatty acids are in the jet fuel range. Thereby, this work investigated the composition and physicochemical characterization of licuri oil and licuri biodiesel, both with satisfactory results according to international standards, with the purpose of obtaining hydrocarbons in the range of jet fuel from these feedstock, by catalytic deoxygenation. The semi-batch reaction, using a 5% Pd/C catalyst at 300 °C and 207 psi, produced n-alkanes with a conversion of up to 39.2%. The n-alkane selectivity was 80.7%, in addition to CO(2) selectivity of 83.4% for biodiesel, indicating the preference for the decarboxylation pathway and also confirming licuri as a potential raw material for biojet fuel.
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spelling pubmed-67769662019-10-07 Catalytic Deoxygenation of the Oil and Biodiesel of Licuri (Syagrus coronata) To Obtain n-Alkanes with Chains in the Range of Biojet Fuels Araújo, Pedro H. M. Maia, Ary S. Cordeiro, Angela M. T. M. Gondim, Amanda D. Santos, Nataly A. ACS Omega [Image: see text] Aviation industry has the challenge of halving CO(2) emissions by 2050, as compared to 2005. An alternative are drop-in biofuels, which are sustainable and fully compatible with aircraft engines and also can be mixed with fossil jet fuel. Among the feedstock for biojet fuel production, licuri (Syagrus coronata) can be highlighted as most of its fatty acids are in the jet fuel range. Thereby, this work investigated the composition and physicochemical characterization of licuri oil and licuri biodiesel, both with satisfactory results according to international standards, with the purpose of obtaining hydrocarbons in the range of jet fuel from these feedstock, by catalytic deoxygenation. The semi-batch reaction, using a 5% Pd/C catalyst at 300 °C and 207 psi, produced n-alkanes with a conversion of up to 39.2%. The n-alkane selectivity was 80.7%, in addition to CO(2) selectivity of 83.4% for biodiesel, indicating the preference for the decarboxylation pathway and also confirming licuri as a potential raw material for biojet fuel. American Chemical Society 2019-09-19 /pmc/articles/PMC6776966/ /pubmed/31592170 http://dx.doi.org/10.1021/acsomega.9b01737 Text en Copyright © 2019 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Araújo, Pedro H. M.
Maia, Ary S.
Cordeiro, Angela M. T. M.
Gondim, Amanda D.
Santos, Nataly A.
Catalytic Deoxygenation of the Oil and Biodiesel of Licuri (Syagrus coronata) To Obtain n-Alkanes with Chains in the Range of Biojet Fuels
title Catalytic Deoxygenation of the Oil and Biodiesel of Licuri (Syagrus coronata) To Obtain n-Alkanes with Chains in the Range of Biojet Fuels
title_full Catalytic Deoxygenation of the Oil and Biodiesel of Licuri (Syagrus coronata) To Obtain n-Alkanes with Chains in the Range of Biojet Fuels
title_fullStr Catalytic Deoxygenation of the Oil and Biodiesel of Licuri (Syagrus coronata) To Obtain n-Alkanes with Chains in the Range of Biojet Fuels
title_full_unstemmed Catalytic Deoxygenation of the Oil and Biodiesel of Licuri (Syagrus coronata) To Obtain n-Alkanes with Chains in the Range of Biojet Fuels
title_short Catalytic Deoxygenation of the Oil and Biodiesel of Licuri (Syagrus coronata) To Obtain n-Alkanes with Chains in the Range of Biojet Fuels
title_sort catalytic deoxygenation of the oil and biodiesel of licuri (syagrus coronata) to obtain n-alkanes with chains in the range of biojet fuels
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6776966/
https://www.ncbi.nlm.nih.gov/pubmed/31592170
http://dx.doi.org/10.1021/acsomega.9b01737
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