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Electrically Conductive Gels Prepared from Syndiotactic Polystyrene and an Ionic Liquid

[Image: see text] Syndiotactic polystyrene (SPS) physical gels containing a large amount of the ionic liquid 1-butylpyridinium bromide ([C(4)py]Br) were systematically prepared and their physical properties were examined in detail. The gels had stable forms for a long time, having storage elastic mo...

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Detalles Bibliográficos
Autores principales: Itagaki, Hideyuki, Yoshida, Naoto, Sano, Takumi, Yokoyama, Mayu, Iba, Nozomi, Sugiyama, Ryotaro, Kuroki, Masakatsu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6777124/
https://www.ncbi.nlm.nih.gov/pubmed/31592126
http://dx.doi.org/10.1021/acsomega.9b02310
Descripción
Sumario:[Image: see text] Syndiotactic polystyrene (SPS) physical gels containing a large amount of the ionic liquid 1-butylpyridinium bromide ([C(4)py]Br) were systematically prepared and their physical properties were examined in detail. The gels had stable forms for a long time, having storage elastic modulus values of normal gels. They showed nearly the same values of the electrical conductivity (∼7 mS/cm) as those of the mixed solutions of [C(4)py]Br, suggesting that the distribution of [C(4)py]Br was uniform in these gels and that the charge transportation in these SPS gels was not interrupted by a three-dimensional network of SPS fibrils consisting of the SPS δ crystalline phases.