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Electrically Conductive Gels Prepared from Syndiotactic Polystyrene and an Ionic Liquid
[Image: see text] Syndiotactic polystyrene (SPS) physical gels containing a large amount of the ionic liquid 1-butylpyridinium bromide ([C(4)py]Br) were systematically prepared and their physical properties were examined in detail. The gels had stable forms for a long time, having storage elastic mo...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2019
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6777124/ https://www.ncbi.nlm.nih.gov/pubmed/31592126 http://dx.doi.org/10.1021/acsomega.9b02310 |
Sumario: | [Image: see text] Syndiotactic polystyrene (SPS) physical gels containing a large amount of the ionic liquid 1-butylpyridinium bromide ([C(4)py]Br) were systematically prepared and their physical properties were examined in detail. The gels had stable forms for a long time, having storage elastic modulus values of normal gels. They showed nearly the same values of the electrical conductivity (∼7 mS/cm) as those of the mixed solutions of [C(4)py]Br, suggesting that the distribution of [C(4)py]Br was uniform in these gels and that the charge transportation in these SPS gels was not interrupted by a three-dimensional network of SPS fibrils consisting of the SPS δ crystalline phases. |
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