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A Bilayer 2D-WS(2)/Organic-Based Heterojunction for High-Performance Photodetectors

Two-dimensional (2D) tungsten disulfide (WS(2)) has inspired great efforts in optoelectronics, such as in solar cells, light-emitting diodes, and photodetectors. However, chemical vapor deposition (CVD) grown 2D WS(2) domains with the coexistence of a discontinuous single layer and multilayers are s...

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Autores principales: Huang, Feng, Li, Jing Zhou, Xu, Zhu Hua, Liu, Yuan, Luo, Ri Peng, Zhang, Si Wei, Nie, Peng Bo, Lv, Yan Fei, Zhao, Shi Xi, Su, Wei Tao, Li, Wen Di, Zhao, Shi Chao, Wei, Guo Dan, Kuo, Hao Chung, Kang, Fei Yu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6781271/
https://www.ncbi.nlm.nih.gov/pubmed/31540315
http://dx.doi.org/10.3390/nano9091312
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author Huang, Feng
Li, Jing Zhou
Xu, Zhu Hua
Liu, Yuan
Luo, Ri Peng
Zhang, Si Wei
Nie, Peng Bo
Lv, Yan Fei
Zhao, Shi Xi
Su, Wei Tao
Li, Wen Di
Zhao, Shi Chao
Wei, Guo Dan
Kuo, Hao Chung
Kang, Fei Yu
author_facet Huang, Feng
Li, Jing Zhou
Xu, Zhu Hua
Liu, Yuan
Luo, Ri Peng
Zhang, Si Wei
Nie, Peng Bo
Lv, Yan Fei
Zhao, Shi Xi
Su, Wei Tao
Li, Wen Di
Zhao, Shi Chao
Wei, Guo Dan
Kuo, Hao Chung
Kang, Fei Yu
author_sort Huang, Feng
collection PubMed
description Two-dimensional (2D) tungsten disulfide (WS(2)) has inspired great efforts in optoelectronics, such as in solar cells, light-emitting diodes, and photodetectors. However, chemical vapor deposition (CVD) grown 2D WS(2) domains with the coexistence of a discontinuous single layer and multilayers are still not suitable for the fabrication of photodetectors on a large scale. An emerging field in the integration of organic materials with 2D materials offers the advantages of molecular diversity and flexibility to provide an exciting aspect on high-performance device applications. Herein, we fabricated a photodetector based on a 2D-WS(2)/organic semiconductor materials (mixture of the (Poly-(N,N′-bis-4-butylphenyl-N,N′-bisphenyl) benzidine and Phenyl-C61-butyric acid methyl ester (Poly-TPD/PCBM)) heterojunction. The application of Poly-TPD/PCBM organic blend film enhanced light absorption, electrically connected the isolated WS(2) domains, and promoted the separation of electron-hole pairs. The generated exciton could sufficiently diffuse to the interface of the WS(2) and the organic blend layers for efficient charge separation, where Poly-TPD was favorable for hole carrier transport and PCBM for electron transport to their respective electrodes. We show that the photodetector exhibited high responsivity, detectivity, and an on/off ratio of 0.1 A/W, 1.1 × 10(11) Jones, and 100, respectively. In addition, the photodetector showed a broad spectral response from 500 nm to 750 nm, with a peak external quantum efficiency (EQE) of 8%. Our work offers a facile solution-coating process combined with a CVD technique to prepare an inorganic/organic heterojunction photodetector with high performance on silicon substrate.
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spelling pubmed-67812712019-10-30 A Bilayer 2D-WS(2)/Organic-Based Heterojunction for High-Performance Photodetectors Huang, Feng Li, Jing Zhou Xu, Zhu Hua Liu, Yuan Luo, Ri Peng Zhang, Si Wei Nie, Peng Bo Lv, Yan Fei Zhao, Shi Xi Su, Wei Tao Li, Wen Di Zhao, Shi Chao Wei, Guo Dan Kuo, Hao Chung Kang, Fei Yu Nanomaterials (Basel) Article Two-dimensional (2D) tungsten disulfide (WS(2)) has inspired great efforts in optoelectronics, such as in solar cells, light-emitting diodes, and photodetectors. However, chemical vapor deposition (CVD) grown 2D WS(2) domains with the coexistence of a discontinuous single layer and multilayers are still not suitable for the fabrication of photodetectors on a large scale. An emerging field in the integration of organic materials with 2D materials offers the advantages of molecular diversity and flexibility to provide an exciting aspect on high-performance device applications. Herein, we fabricated a photodetector based on a 2D-WS(2)/organic semiconductor materials (mixture of the (Poly-(N,N′-bis-4-butylphenyl-N,N′-bisphenyl) benzidine and Phenyl-C61-butyric acid methyl ester (Poly-TPD/PCBM)) heterojunction. The application of Poly-TPD/PCBM organic blend film enhanced light absorption, electrically connected the isolated WS(2) domains, and promoted the separation of electron-hole pairs. The generated exciton could sufficiently diffuse to the interface of the WS(2) and the organic blend layers for efficient charge separation, where Poly-TPD was favorable for hole carrier transport and PCBM for electron transport to their respective electrodes. We show that the photodetector exhibited high responsivity, detectivity, and an on/off ratio of 0.1 A/W, 1.1 × 10(11) Jones, and 100, respectively. In addition, the photodetector showed a broad spectral response from 500 nm to 750 nm, with a peak external quantum efficiency (EQE) of 8%. Our work offers a facile solution-coating process combined with a CVD technique to prepare an inorganic/organic heterojunction photodetector with high performance on silicon substrate. MDPI 2019-09-13 /pmc/articles/PMC6781271/ /pubmed/31540315 http://dx.doi.org/10.3390/nano9091312 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Huang, Feng
Li, Jing Zhou
Xu, Zhu Hua
Liu, Yuan
Luo, Ri Peng
Zhang, Si Wei
Nie, Peng Bo
Lv, Yan Fei
Zhao, Shi Xi
Su, Wei Tao
Li, Wen Di
Zhao, Shi Chao
Wei, Guo Dan
Kuo, Hao Chung
Kang, Fei Yu
A Bilayer 2D-WS(2)/Organic-Based Heterojunction for High-Performance Photodetectors
title A Bilayer 2D-WS(2)/Organic-Based Heterojunction for High-Performance Photodetectors
title_full A Bilayer 2D-WS(2)/Organic-Based Heterojunction for High-Performance Photodetectors
title_fullStr A Bilayer 2D-WS(2)/Organic-Based Heterojunction for High-Performance Photodetectors
title_full_unstemmed A Bilayer 2D-WS(2)/Organic-Based Heterojunction for High-Performance Photodetectors
title_short A Bilayer 2D-WS(2)/Organic-Based Heterojunction for High-Performance Photodetectors
title_sort bilayer 2d-ws(2)/organic-based heterojunction for high-performance photodetectors
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6781271/
https://www.ncbi.nlm.nih.gov/pubmed/31540315
http://dx.doi.org/10.3390/nano9091312
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